Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written. Concept Introduction: Geometric isomers are the isomers of same compound which differ in the relative positions the atoms occupy in space. For alkene geometric isomers are possible if the carbon atoms in the end of the double bond are not bonded to same groups or atoms. Usually trans isomer is more stable than cis isomer as the steric hindrance will be very less. To Write: The structural formula for trans isomer

Question

Complete the following table. The only density needed is already given. Show your calculations in a neat and easy-to-follow manner in the space below the table. All units should be included and significant figures should be given close attention. Be sure to notice that the amount of material should be in millimoles rather than moles, and the theoretical mass of the product should in milligrams rather than grams. LOCH 3 + H2SO4 HNO 3 O=C-OCH 3 NO2 x H₂O F.W. 4.0 mL 1.3 M amount 0.50 mL in H2SO4 mg Theoretical Theoretical mmoles density 1.09

Answer 1

Question

Chapter 23, Problem 23.80QP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Geometric isomers are the isomers of same compound which differ in the relative positions the atoms occupy in space. For alkene geometric isomers are possible if the carbon atoms in the end of the double bond are not bonded to same groups or atoms. Usually trans isomer is more stable than cis isomer as the steric hindrance will be very less.

To Write: The structural formula for trans isomer

(b)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

If the compound has a unsaturated bond present in it, then the position of the unsaturated bond is mentioned in the IUPAC name itself.

To Write: The structural formula for trans isomer

(c)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Alkenes undergo addition reaction with unsymmetrical reagent and symmetrical reagent. The addition reaction takes place across the double bond. The addition follows Markownikoff’s rule. When halogen is added to an alkene, the halogen atom adds across the double bond.

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

To Write: The condensed structural formula for the major product obtained when the given alkene is treated with Bromine.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

Complete the following table. The only density needed is already given. Show your calculations in a neat and easy-to-follow manner in the space below the table. All units should be included and significant figures should be given close attention. Be sure to notice that the amount of material should be in millimoles rather than moles, and the theoretical mass of the product should in milligrams rather than grams. LOCH 3 + H2SO4 HNO 3 O=C-OCH 3 NO2 x H₂O F.W. 4.0 mL 1.3 M amount 0.50 mL in H2SO4 mg Theoretical Theoretical mmoles density 1.09

Kumada Coupling: 1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a mechanism and give two reasons why you would NOT get the desired product. Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene. Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?

Wintergreen from Aspirin: 1. In isolating the salicylic acid, why is it important to press out as much of the water as possible? 2. Write the mechanism of the esterification reaction you did. 3. What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional group change. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?

Answer 2

Question

Chapter 23, Problem 23.80QP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Geometric isomers are the isomers of same compound which differ in the relative positions the atoms occupy in space. For alkene geometric isomers are possible if the carbon atoms in the end of the double bond are not bonded to same groups or atoms. Usually trans isomer is more stable than cis isomer as the steric hindrance will be very less.

To Write: The structural formula for trans isomer

(b)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

If the compound has a unsaturated bond present in it, then the position of the unsaturated bond is mentioned in the IUPAC name itself.

To Write: The structural formula for trans isomer

(c)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Alkenes undergo addition reaction with unsymmetrical reagent and symmetrical reagent. The addition reaction takes place across the double bond. The addition follows Markownikoff’s rule. When halogen is added to an alkene, the halogen atom adds across the double bond.

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

To Write: The condensed structural formula for the major product obtained when the given alkene is treated with Bromine.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter 23, Problem 23.80QP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Geometric isomers are the isomers of same compound which differ in the relative positions the atoms occupy in space. For alkene geometric isomers are possible if the carbon atoms in the end of the double bond are not bonded to same groups or atoms. Usually trans isomer is more stable than cis isomer as the steric hindrance will be very less.

To Write: The structural formula for trans isomer

(b)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

If the compound has a unsaturated bond present in it, then the position of the unsaturated bond is mentioned in the IUPAC name itself.

To Write: The structural formula for trans isomer

(c)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Alkenes undergo addition reaction with unsymmetrical reagent and symmetrical reagent. The addition reaction takes place across the double bond. The addition follows Markownikoff’s rule. When halogen is added to an alkene, the halogen atom adds across the double bond.

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

To Write: The condensed structural formula for the major product obtained when the given alkene is treated with Bromine.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 23, Problem 23.80QP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Geometric isomers are the isomers of same compound which differ in the relative positions the atoms occupy in space. For alkene geometric isomers are possible if the carbon atoms in the end of the double bond are not bonded to same groups or atoms. Usually trans isomer is more stable than cis isomer as the steric hindrance will be very less.

To Write: The structural formula for trans isomer

(b)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

If the compound has a unsaturated bond present in it, then the position of the unsaturated bond is mentioned in the IUPAC name itself.

To Write: The structural formula for trans isomer

(c)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Alkenes undergo addition reaction with unsymmetrical reagent and symmetrical reagent. The addition reaction takes place across the double bond. The addition follows Markownikoff’s rule. When halogen is added to an alkene, the halogen atom adds across the double bond.

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

To Write: The condensed structural formula for the major product obtained when the given alkene is treated with Bromine.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter 23, Problem 23.80QP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Geometric isomers are the isomers of same compound which differ in the relative positions the atoms occupy in space. For alkene geometric isomers are possible if the carbon atoms in the end of the double bond are not bonded to same groups or atoms. Usually trans isomer is more stable than cis isomer as the steric hindrance will be very less.

To Write: The structural formula for trans isomer

(b)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

If the compound has a unsaturated bond present in it, then the position of the unsaturated bond is mentioned in the IUPAC name itself.

To Write: The structural formula for trans isomer

(c)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Alkenes undergo addition reaction with unsymmetrical reagent and symmetrical reagent. The addition reaction takes place across the double bond. The addition follows Markownikoff’s rule. When halogen is added to an alkene, the halogen atom adds across the double bond.

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

To Write: The condensed structural formula for the major product obtained when the given alkene is treated with Bromine.

Answer 6

Chapter 23, Problem 23.80QP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Geometric isomers are the isomers of same compound which differ in the relative positions the atoms occupy in space. For alkene geometric isomers are possible if the carbon atoms in the end of the double bond are not bonded to same groups or atoms. Usually trans isomer is more stable than cis isomer as the steric hindrance will be very less.

To Write: The structural formula for trans isomer

Answer 7

Chapter 23, Problem 23.80QP

(a)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Geometric isomers are the isomers of same compound which differ in the relative positions the atoms occupy in space. For alkene geometric isomers are possible if the carbon atoms in the end of the double bond are not bonded to same groups or atoms. Usually trans isomer is more stable than cis isomer as the steric hindrance will be very less.

To Write: The structural formula for trans isomer

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

If the compound has a unsaturated bond present in it, then the position of the unsaturated bond is mentioned in the IUPAC name itself.

To Write: The structural formula for trans isomer

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

If the compound has a unsaturated bond present in it, then the position of the unsaturated bond is mentioned in the IUPAC name itself.

To Write: The structural formula for trans isomer

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Alkenes undergo addition reaction with unsymmetrical reagent and symmetrical reagent. The addition reaction takes place across the double bond. The addition follows Markownikoff’s rule. When halogen is added to an alkene, the halogen atom adds across the double bond.

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

To Write: The condensed structural formula for the major product obtained when the given alkene is treated with Bromine.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structural formula of the trans isomer has to be given. The trans isomer has to be named and the condensed structural formula for the major product of reaction with Bromine has to be written.

Concept Introduction:

Alkenes undergo addition reaction with unsymmetrical reagent and symmetrical reagent. The addition reaction takes place across the double bond. The addition follows Markownikoff’s rule. When halogen is added to an alkene, the halogen atom adds across the double bond.

Condensed structural formula is representation of the organic compound. In this the lengthy carbon chain is shown only with the carbon atoms (along with the hydrogen) without any bonds. The additional branches are shown with explicit bonds.

To Write: The condensed structural formula for the major product obtained when the given alkene is treated with Bromine.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 15

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 16

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 17

Trending nowThis is a popular solution!

Answer 18

Trending nowThis is a popular solution!

Answer 19

Trending nowThis is a popular solution!

Answer 20

Trending now

Answer 21

This is a popular solution!

Answer 22

See solution

Check out sample textbook solution

Answer 23

Ch. 23.2 - Prob. 23.1E Ch. 23.2 - In the model shown here, C atoms are black and H...Ch. 23.2 - Prob. 23.2CC Ch. 23.3 - Prob. 23.2E Ch. 23.3 - Prob. 23.3E Ch. 23.5 - Prob. 23.4E Ch. 23.5 - Prob. 23.5E Ch. 23.5 - Prob. 23.6E Ch. 23.5 - Prob. 23.7E Ch. 23.5 - Prob. 23.8E

Solution Summary: The author explains the structure of the trans isomer and the condensed structural formula for the major product of reaction with Bromine.

Chapter 23 Solutions