(a) Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at − 78 ° C is to be drawn. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as S N 2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step. The bulky base like LDA always abstracts the proton from the side of less substituted C − atom .

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Answer 1

Question

Chapter 23, Problem 23.7P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(d)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

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1. 6. Draw the products for the following reaction: 2. Diels-Aider reaction NOH O OH

Answer 2

Question

Chapter 23, Problem 23.7P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(d)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

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Answer 3

Question

Chapter 23, Problem 23.7P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(d)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

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Answer 4

Question

Chapter 23, Problem 23.7P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(d)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

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Answer 5

Chapter 23, Problem 23.7P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Interpretation Introduction

(d)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Answer 6

Chapter 23, Problem 23.7P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Answer 7

Chapter 23, Problem 23.7P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Answer 10

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Answer 11

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Answer 12

Interpretation Introduction

(d)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Answer 13

Interpretation Introduction

(d)

Interpretation: The product that is formed by the reaction of the given starting material with LDA in the presence of THF solution at −78°C is to be drawn.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

The bulky base like LDA always abstracts the proton from the side of less substituted C−atom.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 23 - Problem 23.1 Draw the enol or keto tautomer(s) of...Ch. 23 - Draw a stepwise mechanism for the following...Ch. 23 - Prob. 23.3P Ch. 23 - Prob. 23.4P Ch. 23 - Which CH bonds in the following molecules are...Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - When ethyl acetoacetate (CH3COCH2CO2CH2CH3) is...Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

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