Loose Leaf for Chemistry
13th Edition
ISBN: 9781260162035
Author: Raymond Chang Dr., Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 23, Problem 23.64QP
Interpretation Introduction
Interpretation: The method to distinguish between
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From the following reduction potentials
I2 (s) + 2e- = 2I- (aq) E0= 0.535 V
I2 (aq) + 2e- = 2I- (aq) E0= 0.620 V
I3- (aq) + 2e- = 3I- (aq) E0= 0.535 V
a) Calculate the equilibrium constant for I2 (aq) + I- (aq) = I3- (aq).
b) Calculate the equilibrium constant for I2 (s) + I- (aq) = I3- (aq).
c) Calculate the solubility of I2 (s) in water.
2. (3 pts) Consider the unit cell for the spinel compound,
CrFe204. How many total particles are in the unit cell?
Also, show how the number of particles and their
positions are consistent with the CrFe204
stoichiometry - this may or may not be reflected by the
particle colors in the diagram. (HINT: In the diagram,
the blue particle is in an interior position while each red
particle is either in a corner or face position.)
From the following potentials, calculate the activity of Cl- in saturated KCl.
E0 (calomel electrode)= 0.268 V
E (calomel electrode, saturated KCl)= 0.241 V
Chapter 23 Solutions
Loose Leaf for Chemistry
Ch. 23.1 - Identify the following transition metal atoms and...Ch. 23.3 - Write the oxidation numbers of the metals in the...Ch. 23.3 - Prob. 2PECh. 23.3 - Prob. 3PECh. 23.3 - Prob. 1RCFCh. 23.3 - What is the difference between these two...Ch. 23.3 - Prob. 3RCFCh. 23.4 - Prob. 1RCFCh. 23.5 - Prob. 4PECh. 23.5 - Prob. 1RCF
Ch. 23.5 - Determine the number of unpaired electrons in the...Ch. 23 - What distinguishes a transition metal from a...Ch. 23 - Why is zinc not considered a transition metal?Ch. 23 - Explain why atomic radii decrease very gradually...Ch. 23 - Without referring to the text, write the...Ch. 23 - Write the electron configurations of the following...Ch. 23 - Why do transition metals have more oxidation...Ch. 23 - Prob. 23.7QPCh. 23 - Prob. 23.8QPCh. 23 - Define the following terms: coordination compound,...Ch. 23 - Describe the interaction between a donor atom and...Ch. 23 - Prob. 23.11QPCh. 23 - Prob. 23.12QPCh. 23 - Prob. 23.13QPCh. 23 - Prob. 23.14QPCh. 23 - Prob. 23.15QPCh. 23 - What are the systematic names for the following...Ch. 23 - Prob. 23.17QPCh. 23 - Prob. 23.18QPCh. 23 - Define the following terms: stereoisomers,...Ch. 23 - Prob. 23.20QPCh. 23 - Prob. 23.21QPCh. 23 - Prob. 23.22QPCh. 23 - Prob. 23.23QPCh. 23 - Prob. 23.24QPCh. 23 - Draw structures of all the geometric and optical...Ch. 23 - Prob. 23.26QPCh. 23 - Briefly describe crystal field theory.Ch. 23 - Prob. 23.28QPCh. 23 - What is the origin of color in a coordination...Ch. 23 - Prob. 23.30QPCh. 23 - Prob. 23.31QPCh. 23 - Prob. 23.32QPCh. 23 - Prob. 23.33QPCh. 23 - Prob. 23.34QPCh. 23 - Prob. 23.35QPCh. 23 - The absorption maximum for the complex ion...Ch. 23 - Prob. 23.37QPCh. 23 - A solution made by dissolving 0.875 g of...Ch. 23 - Prob. 23.39QPCh. 23 - Prob. 23.40QPCh. 23 - Prob. 23.41QPCh. 23 - The [Fe(CN)6]3 complex is more labile than the...Ch. 23 - Aqueous copper(II) sulfate solution is blue in...Ch. 23 - When aqueous potassium cyanide is added to a...Ch. 23 - A concentrated aqueous copper(II) chloride...Ch. 23 - Prob. 23.46QPCh. 23 - As we read across the first-row transition metals...Ch. 23 - Prob. 23.48QPCh. 23 - Prob. 23.49QPCh. 23 - Prob. 23.50QPCh. 23 - Prob. 23.51QPCh. 23 - Chemical analysis shows that hemoglobin contains...Ch. 23 - Explain the following facts: (a) Copper and iron...Ch. 23 - A student in 1895 prepared three coordination...Ch. 23 - Prob. 23.55QPCh. 23 - From the standard reduction potentials listed in...Ch. 23 - Using the standard reduction potentials listed in...Ch. 23 - The Co2+-porphyrin complex is more stable than the...Ch. 23 - Prob. 23.59QPCh. 23 - Prob. 23.60QPCh. 23 - Hydrated Mn2+ ions are practically colorless (see...Ch. 23 - Which of the following hydrated cations are...Ch. 23 - Prob. 23.63QPCh. 23 - Prob. 23.64QPCh. 23 - Prob. 23.65QPCh. 23 - Prob. 23.66QPCh. 23 - The compound 1,1,1-trifluoroacetylacetone (tfa) is...Ch. 23 - Prob. 23.68QPCh. 23 - Prob. 23.69QPCh. 23 - Prob. 23.70QPCh. 23 - Prob. 23.71QPCh. 23 - Commercial silver-plating operations frequently...Ch. 23 - Draw qualitative diagrams for the crystal field...Ch. 23 - (a) The free Cu(I) ion is unstable in solution and...Ch. 23 - Prob. 23.75QPCh. 23 - Prob. 23.76QP
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- 2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); H₂O (B); Reagents: HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); H₂O2/HO (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI + enant OH Solvent Reagent(s) Solvent Reagent(s)arrow_forwardGermanium (Ge) is a semiconductor with a bandgap of 2.2 eV. How could you dope Ge to make it a p-type semiconductor with a larger bandgap? Group of answer choices It is impossible to dope Ge and have this result in a larger bandgap. Dope the Ge with silicon (Si) Dope the Ge with gallium (Ga) Dope the Ge with phosphorus (P)arrow_forwardWhich of the following semiconductors would you choose to have photons with the longest possible wavelengths be able to promote electrons to the semiconductor's conduction band? Group of answer choices Si Ge InSb CdSarrow_forward
- Which of the following metals is the only one with all of its bands completely full? Group of answer choices K Na Ca Alarrow_forward2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each reagent set. If a reaction cannot be carried out with reagents (sets) class, write NP (not possible) in the solvent box for reagent set #1. Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s). Solvents: CH2Cl2 (A); Reagents: H₂O (B); CH3CO₂H (D) NaHCO3 (4); Hg(OAc)2 (5); HBr (1); R₂BH (6); H2SO4 (2); CH3OH (C); Br₂ (3); H₂O₂ / HO- (7); NaBH4 (8) Reagent Set #1 Reagent Set #2 FGI OH - α-α Br + enant Solvent Reagent(s) Solvent Reagent(s)arrow_forwardBased on concepts from Lecture 3-5, which of the following ionic compounds should be most soluble in water? Group of answer choices MgO BeO CaO BaOarrow_forward
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