Concept explainers
(a)
Interpretation: To identify the compound among ATP and creatine phosphate that releases more energy upon hydrolysis.
Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.
Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.
(b)
Interpretation: To identify the compound among
Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.
Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.
(c)
Interpretation: To identify the compound among ADP and AMP that releases more energy upon hydrolysis.
Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.
Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.
(d)
Interpretation: To identify the compound among Phosphoenolpyruvate and
Concept introduction: High-energy compounds are those compounds that release a large amount of energy upon hydrolysis. These compounds consist of highly strained bonds which are responsible for the release of a high amount of energy. The compounds containing a phosphate group are examples of high energy compound.
Free energy on hydrolysis is considered as a parameter for determining the strain in the bonds. Greater the strain in the bond more will be the negative value of free energy on hydrolysis and vice-versa.
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Chapter 23 Solutions
GENERAL,ORGANIC,+BIO.CHEM.-MINDTAP
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- Draw the mechanism for the following Friedel-Craft reaction. AlBr3 Brarrow_forward(a) Draw the structures of A and B in the following reaction. (i) NaNH2, NH3(1) A + B (ii) H3O+arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Consider the following decomposition reaction of N2O5(g): For the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 → NO2 + NO3 (K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Indicate whether the following rate expression is acceptable: d[N2O5] = -k₁[N₂O₂] + K¸₁[NO₂][NO3] - K¸[NO₂]³ dtarrow_forwardIn a reaction of A + B to give C, another compound other than A, B or C may appear in the kinetic equation.arrow_forwardFor the reaction 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 →> NO₂+ NO3_(K1) NO2 + NO3 → N2O5 (k-1) NO2 + NO3 → → NO2 + O2 + NO (K2) NO + N2O5- NO2 + NO2 + NO2 (K3) d[N₂O5] __2k‚k₂[N2O5] Indicate whether the following rate expression is acceptable: dt k₁₁+ k₂arrow_forward
- Given the reaction R + Q → P, indicate the rate law with respect to R, with respect to P and with respect to P.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardk₁ Given the reaction A B, indicate k-1 d[A] (A). the rate law with respect to A: (B). the rate law with respect to B: d[B] dt dtarrow_forward
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