Chemistry: The Molecular Nature of Matter and Change
9th Edition
ISBN: 9781260477467
Author: Martin Silberberg
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 23, Problem 23.35P
Interpretation Introduction
Interpretation:
The makeup of a complex ion, including the nature of the ligands and their interactions with the central metal ion has to be described. A complex ion can be positive or negative has to be explained.
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For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
×
NO2
○ donating
O donating
O withdrawing
O withdrawing
O electron-rich
electron-deficient
no inductive effects
O no resonance effects
O similar to benzene
E
[
CI
O donating
withdrawing
O no inductive effects
Explanation
Check
○ donating
withdrawing
no resonance effects
electron-rich
electron-deficient
O similar to benzene
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Chapter 23 Solutions
Chemistry: The Molecular Nature of Matter and Change
Ch. 23.1 - Write partial electron configurations (no noble...Ch. 23.1 - Find the charge of each of the following ions,...Ch. 23.2 - Prob. 23.2AFPCh. 23.2 - Prob. 23.2BFPCh. 23.3 - Give the coordination number and the charge of the...Ch. 23.3 - Write the formula of the coordination compound...Ch. 23.3 - Prob. 23.4AFPCh. 23.3 - Prob. 23.4BFPCh. 23.3 - Prob. 23.5AFPCh. 23.3 - Prob. 23.5BFP
Ch. 23.4 - Prob. 23.6AFPCh. 23.4 - Prob. 23.6BFPCh. 23.4 - Prob. 23.7AFPCh. 23.4 - Prob. 23.7BFPCh. 23 - Prob. 23.1PCh. 23 - Write the general electron configuration of a...Ch. 23 - Prob. 23.3PCh. 23 - Prob. 23.4PCh. 23 - Prob. 23.5PCh. 23 - Prob. 23.6PCh. 23 - (a) What is the range in electronegativity across...Ch. 23 - (a) Explain the major difference between the...Ch. 23 - (a) What behavior distinguishes paramagnetic and...Ch. 23 - Prob. 23.10PCh. 23 - Using the periodic table to locate each element,...Ch. 23 - Using the periodic table to locate each element,...Ch. 23 - Using the periodic table to locate each element,...Ch. 23 - Prob. 23.14PCh. 23 - Prob. 23.15PCh. 23 - What is the highest oxidation state for (a) Ta;...Ch. 23 - What is the highest oxidation state for (a) Nb;...Ch. 23 - Prob. 23.18PCh. 23 - Prob. 23.19PCh. 23 - Prob. 23.20PCh. 23 - Prob. 23.21PCh. 23 - Prob. 23.22PCh. 23 - Prob. 23.23PCh. 23 - Prob. 23.24PCh. 23 - Prob. 23.25PCh. 23 - Prob. 23.26PCh. 23 - What atomic property of the lanthanides leads to...Ch. 23 - Prob. 23.28PCh. 23 - Prob. 23.29PCh. 23 - Give the electron configuration of (a) La; (b)...Ch. 23 - Prob. 23.31PCh. 23 - Only a few lanthanides show an oxidation state...Ch. 23 - Prob. 23.33PCh. 23 - Prob. 23.34PCh. 23 - Describe the makeup of a complex ion, including...Ch. 23 - Prob. 23.36PCh. 23 - Prob. 23.37PCh. 23 - Prob. 23.38PCh. 23 - Prob. 23.39PCh. 23 - Prob. 23.40PCh. 23 - Prob. 23.41PCh. 23 - Prob. 23.42PCh. 23 - Prob. 23.43PCh. 23 - Prob. 23.44PCh. 23 - Prob. 23.45PCh. 23 - Prob. 23.46PCh. 23 - What are the charge and coordination number of the...Ch. 23 - What are the charge and coordination number of the...Ch. 23 - Prob. 23.49PCh. 23 - Give systematic names for the following...Ch. 23 - What are the charge and coordination number of the...Ch. 23 - What are the charge and coordination number of the...Ch. 23 - Prob. 23.53PCh. 23 - Prob. 23.54PCh. 23 - Prob. 23.55PCh. 23 - Prob. 23.56PCh. 23 - Prob. 23.57PCh. 23 - Prob. 23.58PCh. 23 - Prob. 23.59PCh. 23 - Prob. 23.60PCh. 23 - Prob. 23.61PCh. 23 - Prob. 23.62PCh. 23 - For any of the following that can exist as...Ch. 23 - Prob. 23.64PCh. 23 - Prob. 23.65PCh. 23 - Prob. 23.66PCh. 23 - Chromium(III), like cobalt(III), has a...Ch. 23 - When MCl4(NH3)2 is dissolved in water and treated...Ch. 23 - Prob. 23.69PCh. 23 -
What is a coordinate covalent bond?
Is such a...Ch. 23 - Prob. 23.71PCh. 23 - Prob. 23.72PCh. 23 - Prob. 23.73PCh. 23 - In terms of the theory of color absorption,...Ch. 23 - Prob. 23.75PCh. 23 - Prob. 23.76PCh. 23 - Prob. 23.77PCh. 23 - How do the relative magnitudes of Epairing and Δ...Ch. 23 - Prob. 23.79PCh. 23 - Give the number of d electrons (n of dn) for the...Ch. 23 - Give the number of d electrons (n of dn) for the...Ch. 23 - Prob. 23.82PCh. 23 - How many d electrons (n of dn) are in the central...Ch. 23 - Prob. 23.84PCh. 23 - Prob. 23.85PCh. 23 - Prob. 23.86PCh. 23 - Prob. 23.87PCh. 23 - Prob. 23.88PCh. 23 - Prob. 23.89PCh. 23 - Prob. 23.90PCh. 23 - Prob. 23.91PCh. 23 - Prob. 23.92PCh. 23 - Prob. 23.93PCh. 23 - Prob. 23.94PCh. 23 - Prob. 23.95PCh. 23 - Prob. 23.96PCh. 23 - Prob. 23.97PCh. 23 - Prob. 23.98PCh. 23 - When neptunium (Np) and plutonium (Pu) were...Ch. 23 - Prob. 23.100PCh. 23 - Prob. 23.101PCh. 23 - For the compound [Co(en)2Cl2]Cl, give:
The...Ch. 23 - Prob. 23.103PCh. 23 - Prob. 23.104PCh. 23 - Prob. 23.105PCh. 23 - Prob. 23.106PCh. 23 - Prob. 23.107PCh. 23 - Prob. 23.108PCh. 23 - Prob. 23.109PCh. 23 - Prob. 23.110PCh. 23 - Prob. 23.111PCh. 23 - The actinides Pa, U, and Np form a series of...Ch. 23 - Prob. 23.113PCh. 23 - Prob. 23.114PCh. 23 - Prob. 23.115PCh. 23 - Prob. 23.116PCh. 23 - Prob. 23.117PCh. 23 - Prob. 23.118PCh. 23 - Prob. 23.119PCh. 23 - Prob. 23.120PCh. 23 - Prob. 23.121PCh. 23 - Prob. 23.122P
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