Mechanism for the formation of the following products is to be proposed. Concept introduction: The number of resonating structure affects the stability of that molecule. Increase in the number of resonating structure increases the stability. In Naphthalene, cations formed at alpha and beta positions both have equal resonating structures; hence the stability depends on aromaticity. Benzenoid structure is maintained in one while disturbed in another, giving one major and one minor product.

Question

5. Compressibility (6 points total). The isothermal compressibility is a measure of how hard/easy it is to compress an object (how squishy is it?) at constant temperature. It is др defined as Br=-()=-(200²)T' (a) You might wonder why there is a negative sign in this formula. What does it mean when this quantity is positive and what does it mean when this quantity is negative? (b) Derive the formula for the isothermal compressibility of an ideal gas (it is very simple!) (c) Explain under what conditions for the ideal gas the compressibility is higher or lower, and why that makes sense.

Answer 1

Question

Chapter 23, Problem 23.18P

Interpretation Introduction

Interpretation:

Mechanism for the formation of the following products is to be proposed.

Concept introduction:

The number of resonating structure affects the stability of that molecule. Increase in the number of resonating structure increases the stability. In Naphthalene, cations formed at alpha and beta positions both have equal resonating structures; hence the stability depends on aromaticity. Benzenoid structure is maintained in one while disturbed in another, giving one major and one minor product.

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