(a) Interpretation: The theoretical potential of the cell SCE || Fe 3 + ( 0.0150 M), Fe 2 + ( 0.0250 M)| Pt should be calculated. Concept introduction: Nernst equation gives the cell potential under non-standard conditions. E = E 0 − 2.303 R T n F log Q E − cell potential E 0 − standard cell potential R − universal gas constant T − temperature in Kelvin n − number of electrons transferred F − Faraday constant Q − Reaction quotient E c e l l = E c a t h o d e 0 − E a n o d e 0

Question

Name 1) 3-fluoro, 1-butene 2) 2-heptene 2,3-difluoro- 1-pentene 4) 6-iodo,4-methyl- 2-decyne 5) 4,4-dibromo- 1,2-butandiol Complete structural formula F -C=C-C-C- Line formula Condensed structural formula N F CH2=CHCHFCH3

Answer 1

Question

Chapter 23, Problem 23.13QAP

Interpretation Introduction

(a)

Interpretation:

The theoretical potential of the cell SCE || Fe3+(0.0150 M), Fe2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(b)

Interpretation:

The theoretical potential of the cell SCE || Zn2+(0.00135 M)| Zn should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(c)

Interpretation:

The theoretical potential of the cell Saturated Ag/AgCl reference || Ti3+(0.0450 M), Ti2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(d)

Interpretation:

The Theoretical potential of the cell Saturated Ag/AgCl reference || I3−(0.00667 M), I−(0.00433 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

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Name 1) 3-fluoro, 1-butene 2) 2-heptene 2,3-difluoro- 1-pentene 4) 6-iodo,4-methyl- 2-decyne 5) 4,4-dibromo- 1,2-butandiol Complete structural formula F -C=C-C-C- Line formula Condensed structural formula N F CH2=CHCHFCH3

1. Part 1: Naming Organic Compounds он H₁C-C-CH3 CH3 Br CI CI 2. Br-CH-CH-CH₂ H₂C-CH-C= -CH-CH2-CH3 3. HC-CH-CH-C-OH 5. H₂C-CH-CH₂-OH 7. OH 4. CH CH₂-CH₂ 6. сно CH-CH-CH-CH₂-CH₂ H₁₂C-CH-CH-CH-CH₁₂-CH₁₂ 8. OH

11 Organic Chemistry Organic Nomenclature Practice Name/Functional Group n-butane Formula Structural Formula (1) C4tt10 H3C C- (2) CH3CH2CH2 CH 3 H₂ -CH3 Н2 name & functional group (1) and (2) OH H₁₂C Н2 name only (1) and (2) name only (1) and (2) H₁C - = - CH₂ Н2 HC=C-C CH3

Answer 2

Question

Chapter 23, Problem 23.13QAP

Interpretation Introduction

(a)

Interpretation:

The theoretical potential of the cell SCE || Fe3+(0.0150 M), Fe2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(b)

Interpretation:

The theoretical potential of the cell SCE || Zn2+(0.00135 M)| Zn should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(c)

Interpretation:

The theoretical potential of the cell Saturated Ag/AgCl reference || Ti3+(0.0450 M), Ti2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(d)

Interpretation:

The Theoretical potential of the cell Saturated Ag/AgCl reference || I3−(0.00667 M), I−(0.00433 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

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Answer 3

Question

Chapter 23, Problem 23.13QAP

Interpretation Introduction

(a)

Interpretation:

The theoretical potential of the cell SCE || Fe3+(0.0150 M), Fe2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(b)

Interpretation:

The theoretical potential of the cell SCE || Zn2+(0.00135 M)| Zn should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(c)

Interpretation:

The theoretical potential of the cell Saturated Ag/AgCl reference || Ti3+(0.0450 M), Ti2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(d)

Interpretation:

The Theoretical potential of the cell Saturated Ag/AgCl reference || I3−(0.00667 M), I−(0.00433 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

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Answer 4

Question

Chapter 23, Problem 23.13QAP

Interpretation Introduction

(a)

Interpretation:

The theoretical potential of the cell SCE || Fe3+(0.0150 M), Fe2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(b)

Interpretation:

The theoretical potential of the cell SCE || Zn2+(0.00135 M)| Zn should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(c)

Interpretation:

The theoretical potential of the cell Saturated Ag/AgCl reference || Ti3+(0.0450 M), Ti2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(d)

Interpretation:

The Theoretical potential of the cell Saturated Ag/AgCl reference || I3−(0.00667 M), I−(0.00433 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

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Answer 5

Chapter 23, Problem 23.13QAP

Interpretation Introduction

(a)

Interpretation:

The theoretical potential of the cell SCE || Fe3+(0.0150 M), Fe2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(b)

Interpretation:

The theoretical potential of the cell SCE || Zn2+(0.00135 M)| Zn should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(c)

Interpretation:

The theoretical potential of the cell Saturated Ag/AgCl reference || Ti3+(0.0450 M), Ti2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Interpretation Introduction

(d)

Interpretation:

The Theoretical potential of the cell Saturated Ag/AgCl reference || I3−(0.00667 M), I−(0.00433 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Answer 6

Chapter 23, Problem 23.13QAP

Interpretation Introduction

(a)

Interpretation:

The theoretical potential of the cell SCE || Fe3+(0.0150 M), Fe2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Answer 7

Chapter 23, Problem 23.13QAP

Interpretation Introduction

(a)

Interpretation:

The theoretical potential of the cell SCE || Fe3+(0.0150 M), Fe2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Answer 8

Interpretation Introduction

(b)

Interpretation:

The theoretical potential of the cell SCE || Zn2+(0.00135 M)| Zn should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Answer 9

Interpretation Introduction

(b)

Interpretation:

The theoretical potential of the cell SCE || Zn2+(0.00135 M)| Zn should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Answer 10

Interpretation Introduction

(c)

Interpretation:

The theoretical potential of the cell Saturated Ag/AgCl reference || Ti3+(0.0450 M), Ti2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Answer 11

Interpretation Introduction

(c)

Interpretation:

The theoretical potential of the cell Saturated Ag/AgCl reference || Ti3+(0.0450 M), Ti2+(0.0250 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Answer 12

Interpretation Introduction

(d)

Interpretation:

The Theoretical potential of the cell Saturated Ag/AgCl reference || I3−(0.00667 M), I−(0.00433 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Answer 13

Interpretation Introduction

(d)

Interpretation:

The Theoretical potential of the cell Saturated Ag/AgCl reference || I3−(0.00667 M), I−(0.00433 M)| Pt should be calculated.

Concept introduction:

Nernst equation gives the cell potential under non-standard conditions.

E=E0−2.303RTnFlogQ

E − cell potential

E⁰ − standard cell potential

R − universal gas constant

T − temperature in Kelvin

n − number of electrons transferred

F − Faraday constant

Q − Reaction quotient

Ecell=Ecathode0−Eanode0

Answer 14

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Ch. 23 - Prob. 23.1QAP Ch. 23 - Prob. 23.2QAP Ch. 23 - Prob. 23.3QAP Ch. 23 - Prob. 23.4QAP Ch. 23 - Prob. 23.5QAP Ch. 23 - Prob. 23.6QAP Ch. 23 - Prob. 23.7QAP Ch. 23 - Prob. 23.8QAP Ch. 23 - Prob. 23.9QAP Ch. 23 - List the advantages and disadvantages of a...

Chapter 23 Solutions