The changes of the product and reactant particle has to be predicted. Concept introduction: Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change , while irreversible processes always increase the total entropy .

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Answer 1

Question

Chapter 23, Problem 23.118P

(a)

Interpretation Introduction

Interpretation:

The changes of the product and reactant particle has to be predicted.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

(b)

Interpretation Introduction

Interpretation:

The ethylenediamine complex is more stable with respect to ligand exchange with water has to be explained.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

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Answer 2

Question

Chapter 23, Problem 23.118P

(a)

Interpretation Introduction

Interpretation:

The changes of the product and reactant particle has to be predicted.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

(b)

Interpretation Introduction

Interpretation:

The ethylenediamine complex is more stable with respect to ligand exchange with water has to be explained.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Expert Solution & Answer

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See solution

Answer 3

Question

Chapter 23, Problem 23.118P

(a)

Interpretation Introduction

Interpretation:

The changes of the product and reactant particle has to be predicted.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

(b)

Interpretation Introduction

Interpretation:

The ethylenediamine complex is more stable with respect to ligand exchange with water has to be explained.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 23, Problem 23.118P

(a)

Interpretation Introduction

Interpretation:

The changes of the product and reactant particle has to be predicted.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

(b)

Interpretation Introduction

Interpretation:

The ethylenediamine complex is more stable with respect to ligand exchange with water has to be explained.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Expert Solution & Answer

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Answer 5

Chapter 23, Problem 23.118P

(a)

Interpretation Introduction

Interpretation:

The changes of the product and reactant particle has to be predicted.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

(b)

Interpretation Introduction

Interpretation:

The ethylenediamine complex is more stable with respect to ligand exchange with water has to be explained.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Answer 6

Chapter 23, Problem 23.118P

(a)

Interpretation Introduction

Interpretation:

The changes of the product and reactant particle has to be predicted.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

Answer 7

Chapter 23, Problem 23.118P

(a)

Interpretation Introduction

Interpretation:

The changes of the product and reactant particle has to be predicted.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The ethylenediamine complex is more stable with respect to ligand exchange with water has to be explained.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The ethylenediamine complex is more stable with respect to ligand exchange with water has to be explained.

Concept introduction:

Change in entropy of a system is determined by its initial and final states. In the idealization that a process is reversible, the entropy does not change, while irreversible processes always increase the total entropy.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23.1 - Write partial electron configurations (no noble...Ch. 23.1 - Find the charge of each of the following ions,...Ch. 23.2 - Prob. 23.2AFP Ch. 23.2 - Prob. 23.2BFP Ch. 23.3 - Give the coordination number and the charge of the...Ch. 23.3 - Write the formula of the coordination compound...Ch. 23.3 - Prob. 23.4AFP Ch. 23.3 - Prob. 23.4BFP Ch. 23.3 - Prob. 23.5AFP Ch. 23.3 - Prob. 23.5BFP

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