Concept explainers
(a)
Interpretation: To indicate whether malate undergoes (1) oxidation but not reduction, (2) reduction but not oxidation, (3) both oxidation and reduction or (4) neither oxidation nor reduction in the common
Concept introduction: Common metabolic pathway is the total sum of metabolic reactions that occur in stage third and fourth of the biochemical process or it is defined as the total sum of reactions that occur in the citric acid cycle and electron transport chain and oxidative phosphorylation.
These stages are included in the common metabolic pathway because the reactions in these stages are the same for different kinds of food.
The citric acid cycle is the third stage of the biochemical energy production process. The cycle includes the reactions in which the acetyl part of acetyl CoA is oxidized and leads to the formation of carbon dioxide and
Electron transport chain is a sequence of biochemical reactions in which electrons and hydrogen atoms from the citric acid cycle are transferred to various intermediate carriers and finally reacts with molecular oxygen to form a water molecule.
(b)
Interpretation: To indicate whether NADH undergoes (1) oxidation but not reduction, (2) reduction but not oxidation, (3) both oxidation and reduction or (4) neither oxidation nor reduction in the common metabolic pathway.
Concept introduction: Common metabolic pathway is the total sum of metabolic reactions that occur in stage third and fourth of the biochemical process or it is defined as the total sum of reactions that occur in the citric acid cycle and electron transport chain and oxidative phosphorylation.
These stages are included in the common metabolic pathway because the reactions in these stages are the same for different kinds of food.
The citric acid cycle is the third stage of the biochemical energy production process. The cycle includes the reactions in which the acetyl part of acetyl CoA is oxidized and leads to the formation of carbon dioxide and
Electron transport chain is a sequence of biochemical reactions in which electrons and hydrogen atoms from the citric acid cycle are transferred to various intermediate carriers and finally reacts with molecular oxygen to form a water molecule.
(c)
Interpretation: To indicate whether FAD undergoes (1) oxidation but not reduction, (2) reduction but not oxidation, (3) both oxidation and reduction or (4) neither oxidation nor reduction in the common metabolic pathway.
Concept introduction: Common metabolic pathway is the total sum of metabolic reactions that occur in stage third and fourth of the biochemical process or it is defined as the total sum of reactions that occur in the citric acid cycle and electron transport chain and oxidative phosphorylation.
These stages are included in the common metabolic pathway because the reactions in these stages are the same for different kinds of food.
The citric acid cycle is the third stage of the biochemical energy production process. The cycle includes the reactions in which the acetyl part of acetyl CoA is oxidized and leads to the formation of carbon dioxide and
Electron transport chain is a sequence of biochemical reactions in which electrons and hydrogen atoms from the citric acid cycle are transferred to various intermediate carriers and finally reacts with molecular oxygen to form a water molecule.
(d)
Interpretation: To indicate whether
Concept introduction: Common metabolic pathway is the total sum of metabolic reactions that occur in stage third and fourth of the biochemical process or it is defined as the total sum of reactions that occur in the citric acid cycle and electron transport chain and oxidative phosphorylation.
These stages are included in the common metabolic pathway because the reactions in these stages are the same for different kinds of food.
The citric acid cycle is the third stage of the biochemical energy production process. The cycle includes the reactions in which the acetyl part of acetyl CoA is oxidized and leads to the formation of carbon dioxide and

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Chapter 23 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- Assign this COSY spectrumarrow_forwardCan I please get help with this?arrow_forward1. Draw structures corresponding to each of the following names [3 ONLY]: A. 2,2,2-trichloroethanal (chloral). B. trans-3-isopropylcyclohexanecarbaldehyde C. What is the correct structure for 2-hydroxyacetophenone? Circle the letter of your response. a C 0 OH OH OH HO b. H3C CH 0 H d OH D. Provide IUPAC names for each structure below. 0 H C-H 0 0 CH3 H NO₂ E. The substance formed on addition of water to an aldehyde or ketone is called a hydrate or a/an: a. vicinal diol b. geminal diol C. acetal d. ketalarrow_forward
- Assign this spectrumarrow_forwardRedraw the tripeptide with or without its acidic hydrogensto demonstrate where the total charge of -2 comes from: *see imagearrow_forward2. Consider the data below to answer the following questions. Cyanohydrins are important intermediates in the synthesis of α-hydroxycarboxylic acids from ketones and aldehydes. The nitrile functional group can be hydrolyzed by aqueous acid to yield a carboxylic acid. Nitriles can also be hydrolyzed to carboxylic acids using aqueous base. Unfortunately, when a cyanohydrin is treated with aqueous base the original carbonyl compound is isolated. OH CH-COOH 0 HO CN C H30* C. H H HC N NaOH H₂O C=O 0 cyanohydrin H + NaCN + H₂Oarrow_forward
- Assign all integrated peaksarrow_forward- Consider the data in the Table below to answer the following questions: Acidities of Substituted Benzoic and Acetic Acids pk,s at 25C Y-CH COOH Y Y - CH₂COOH meta para H 4.75 4.19 4.19 2.47 3.64 3.55 3.57 4.09 4.46 CN OCH 3 A. Draw the structure of the strongest acid in the table above. B. Explain why cyanoacetic acid and methoxyacetic acid are more acidic than their correspondingly substituted benzoic acid counterparts.arrow_forwardDraw the curved arrow mechanism for this reaction starting with 2-propanol in sulfuric acid. Show all nonzero formal charges and all nonbonded electrons in each step. Species not involved in a particular step do not need to be included in that step, and resonance forms do not need to be shown. Note that the alcohol is in much higher concentration than H₂O in this reaction. Harrow_forward
- Provide reactions showing the following conversions: * see imagearrow_forward. Draw structures corresponding to each of the following names or Provide IUPAC names for each of the ollowing structures [for 4 ONLY]. A. 2-propylpentanoic acid. B. m-chlorobenzoic acid. D. C. O O HOC(CH2)3COH glutaricadd OH OH H3C CH3 C=C H COOH salicylicadd tiglicadd CH₂C=N Joe Marrow_forward. Provide structure(s) for the starting material(s), reagent(s) or the major organic product(s) of each of the ollowing reactions or sequences of reactions. Show all relevant stereochemistry [five only] A. O B. OET CH3 1. LIAIH, ether 2 H₂O O (CH3)2CH-C-CI + 0 0 ether (CH3)2CH-C-O-C-CH3 CH3 C. 0 OH HO CH3 ° Clarrow_forward
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