EP ORGANIC CHEMISTRY,24 MONTH-OWLV2
9th Edition
ISBN: 9781305084391
Author: McMurry
Publisher: CENGAGE L
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Chapter 22.SE, Problem 26MP
Nonconjugated β, ᵞ-unsaturated
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My question is whether HI adds to both double bonds, and if it doesn't, why not?
Strain Energy for Alkanes
Interaction / Compound kJ/mol kcal/mol
H: H eclipsing
4.0
1.0
H: CH3 eclipsing
5.8
1.4
CH3 CH3 eclipsing
11.0
2.6
gauche butane
3.8
0.9
cyclopropane
115
27.5
cyclobutane
110
26.3
cyclopentane
26.0
6.2
cycloheptane
26.2
6.3
cyclooctane
40.5
9.7
(Calculate your answer to the nearest 0.1 energy unit, and be sure to specify units, kJ/mol or kcal/mol. The answer is case
sensitive.)
H.
H
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A certain half-reaction has a standard reduction potential Ered +1.26 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that
must provide at least 1.10 V of electrical power. The cell will operate under standard conditions.
Note for advanced students: assume the engineer requires this half-reaction to happen at the anode of the cell.
Is there a minimum standard reduction
potential that the half-reaction used at
the cathode of this cell can have?
If so, check the "yes" box and calculate
the minimum. Round your answer to 2
decimal places. If there is no lower
limit, check the "no" box..
Is there a maximum standard reduction
potential that the half-reaction used at
the cathode of this cell can have?
If so, check the "yes" box and calculate
the maximum. Round your answer to 2
decimal places. If there is no upper
limit, check the "no" box.
yes, there is a minimum.
1
red
Πν
no minimum
Oyes, there is a maximum.
0
E
red
Dv
By using the information in the ALEKS…
Chapter 22 Solutions
EP ORGANIC CHEMISTRY,24 MONTH-OWLV2
Ch. 22.1 - Prob. 1PCh. 22.1 - How many acidic hydrogens does each of the...Ch. 22.1 - Prob. 3PCh. 22.3 - Write the complete mechanism for the deuteration...Ch. 22.3 - Prob. 5PCh. 22.4 - If methanol rather than water is added at the end...Ch. 22.5 - Prob. 7PCh. 22.5 - Draw a resonance structure of the acetonitrile...Ch. 22.6 - If methanol rather than water is added at the end...Ch. 22.7 - Prob. 10P
Ch. 22.7 - Draw a resonance structure of the acetonitrile...Ch. 22.7 - Why do you suppose ketone halogenations in acidic...Ch. 22.7 - Prob. 13PCh. 22.7 - Prob. 14PCh. 22.7 - Prob. 15PCh. 22.7 - Prob. 16PCh. 22.SE - Prob. 17VCCh. 22.SE - Prob. 18VCCh. 22.SE - Prob. 19VCCh. 22.SE - Prob. 20MPCh. 22.SE - Predict the product(s) and provide the mechanism...Ch. 22.SE - Predict the product(s) and provide the mechanism...Ch. 22.SE - Prob. 23MPCh. 22.SE - In the Hell–Volhard–Zelinskii reaction, only a...Ch. 22.SE - Prob. 25MPCh. 22.SE - Nonconjugated , -unsaturated ketones, such as...Ch. 22.SE - Prob. 27MPCh. 22.SE - Using curved arrows, propose a mechanism for the...Ch. 22.SE - Prob. 29MPCh. 22.SE - One of the later steps in glucose biosynthesis is...Ch. 22.SE - The Favorskii reaction involves treatment of an...Ch. 22.SE - Treatment of a cyclic ketone with diazomethane is...Ch. 22.SE - Prob. 33MPCh. 22.SE - Amino acids can be prepared by reaction of alkyl...Ch. 22.SE - Amino acids can also be prepared by a two-step...Ch. 22.SE - Heating carvone with aqueous sulfuric acid...Ch. 22.SE - Identify all the acidic hydrogens (pKa 25) in the...Ch. 22.SE - Rank the following compounds in order of...Ch. 22.SE - Prob. 39APCh. 22.SE - Base treatment of the following , -unsaturated...Ch. 22.SE - Prob. 41APCh. 22.SE - Prob. 42APCh. 22.SE - Prob. 43APCh. 22.SE - Which, if any, of the following compounds can be...Ch. 22.SE - Prob. 45APCh. 22.SE - Prob. 46APCh. 22.SE - Prob. 47APCh. 22.SE - How might you convert geraniol into either ethyl...Ch. 22.SE - Prob. 49APCh. 22.SE - One way to determine the number of acidic...Ch. 22.SE - Prob. 51APCh. 22.SE - Prob. 52APCh. 22.SE - Prob. 53APCh. 22.SE - Prob. 54APCh. 22.SE - Prob. 55APCh. 22.SE - Prob. 56APCh. 22.SE - All attempts to isolate primary and secondary...Ch. 22.SE - How would you synthesize the following compounds...Ch. 22.SE - Prob. 59APCh. 22.SE - Prob. 60APCh. 22.SE - Prob. 61APCh. 22.SE - Prob. 62APCh. 22.SE - As far back as the 16th century, South American...Ch. 22.SE - The key step in a reported laboratory synthesis of...Ch. 22.SE - Prob. 65AP
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