Distribution of d-electrons in the complex ion [ N i ( H 2 O ) 6 ] 2 + has to be determined. Concept Introduction: The term Crystal field splitting refers to segregation of d-orbitals in to higher energy orbitals and lower energy orbitals when ligands approaches metal ion to co-ordinate. Crystal field splitting is said to be larger when the energy gap between higher energy d-orbitals and lower energy d-orbitals is larger. Crystal field splitting is said to be smaller when the energy gap between higher energy d-orbitals and lower energy d-orbitals is smaller. Spectrochemical series refers to the arrangement of ligands with respect to crystal field splitting they cause in the d-orbitals of a metal ion. The ligand that causes larger splitting pattern is referred to as stronger ligand. The ligands are arranged in increasing order of crystal field splitting they produce. I − < B r − < S 2 − < S C N − < C l − < N O 3 − < N 3 − < F − < O H − < C 2 O 4 2 − < H 2 O < N C S − < C H 3 C N < p y < N H 3 < e n < b i p y < p h e n < N O 2 − < P P h 3 < C N − < C O The ligand that causes larger crystal field splitting is strong ligand and the ligand that causes smaller splitting is termed as weak ligand. Pairing energy refers to the energy required to pair the electrons - that is energy required to make two electrons to be paired in same orbital with opposite spins. If the pairing energy of a complex is high it means the electrons are difficult to be paired and so the complex will be high spin complex with unpaired electrons. If the pairing energy of a complex is low it means the electrons are readily paired and so the complex will be low spin complex with paired electrons. A complex with high splitting energy will have low pairing energy because high splitting energy indicates larger energy gap between lower and higher energy levels that the electrons need lesser energy to be paired and they tend to remain paired in lower energy orbitals. A complex with low splitting energy will have high pairing energy because low splitting energy indicates smaller energy gap between lower and higher energy levels that the electrons disperse among orbitals more randomly and they need higher energy to be paired.

Question

Want to see the full answer?

Answer 1

Question

Chapter 22.7, Problem 22.5E

Interpretation Introduction

Interpretation:

Distribution of d-electrons in the complex ion [Ni(H2O)6]2+ has to be determined.

Concept Introduction:

The term Crystal field splitting refers to segregation of d-orbitals in to higher energy orbitals and lower energy orbitals when ligands approaches metal ion to co-ordinate. Crystal field splitting is said to be larger when the energy gap between higher energy d-orbitals and lower energy d-orbitals is larger. Crystal field splitting is said to be smaller when the energy gap between higher energy d-orbitals and lower energy d-orbitals is smaller.

Spectrochemical series refers to the arrangement of ligands with respect to crystal field splitting they cause in the d-orbitals of a metal ion. The ligand that causes larger splitting pattern is referred to as stronger ligand.

The ligands are arranged in increasing order of crystal field splitting they produce.

I−<Br−<S2−<SCN−<Cl−<NO3−<N3−<F−<OH−<C2O42−<H2O<NCS−<CH3CN<py<NH3<en<bipy<phen<NO2−<PPh3<CN−<CO

The ligand that causes larger crystal field splitting is strong ligand and the ligand that causes smaller splitting is termed as weak ligand.

Pairing energy refers to the energy required to pair the electrons - that is energy required to make two electrons to be paired in same orbital with opposite spins.

If the pairing energy of a complex is high it means the electrons are difficult to be paired and so the complex will be high spin complex with unpaired electrons. If the pairing energy of a complex is low it means the electrons are readily paired and so the complex will be low spin complex with paired electrons.

A complex with high splitting energy will have low pairing energy because high splitting energy indicates larger energy gap between lower and higher energy levels that the electrons need lesser energy to be paired and they tend to remain paired in lower energy orbitals. A complex with low splitting energy will have high pairing energy because low splitting energy indicates smaller energy gap between lower and higher energy levels that the electrons disperse among orbitals more randomly and they need higher energy to be paired.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

What is the IUPAC name of the following compound? CH₂CH₂ H CI H₂CH₂C H CH₂ Selected Answer: O (35,4R)-4 chloro-3-ethylpentane Correct

Answer 2

Question

Chapter 22.7, Problem 22.5E

Interpretation Introduction

Interpretation:

Distribution of d-electrons in the complex ion [Ni(H2O)6]2+ has to be determined.

Concept Introduction:

The term Crystal field splitting refers to segregation of d-orbitals in to higher energy orbitals and lower energy orbitals when ligands approaches metal ion to co-ordinate. Crystal field splitting is said to be larger when the energy gap between higher energy d-orbitals and lower energy d-orbitals is larger. Crystal field splitting is said to be smaller when the energy gap between higher energy d-orbitals and lower energy d-orbitals is smaller.

Spectrochemical series refers to the arrangement of ligands with respect to crystal field splitting they cause in the d-orbitals of a metal ion. The ligand that causes larger splitting pattern is referred to as stronger ligand.

The ligands are arranged in increasing order of crystal field splitting they produce.

I−<Br−<S2−<SCN−<Cl−<NO3−<N3−<F−<OH−<C2O42−<H2O<NCS−<CH3CN<py<NH3<en<bipy<phen<NO2−<PPh3<CN−<CO

The ligand that causes larger crystal field splitting is strong ligand and the ligand that causes smaller splitting is termed as weak ligand.

Pairing energy refers to the energy required to pair the electrons - that is energy required to make two electrons to be paired in same orbital with opposite spins.

If the pairing energy of a complex is high it means the electrons are difficult to be paired and so the complex will be high spin complex with unpaired electrons. If the pairing energy of a complex is low it means the electrons are readily paired and so the complex will be low spin complex with paired electrons.

A complex with high splitting energy will have low pairing energy because high splitting energy indicates larger energy gap between lower and higher energy levels that the electrons need lesser energy to be paired and they tend to remain paired in lower energy orbitals. A complex with low splitting energy will have high pairing energy because low splitting energy indicates smaller energy gap between lower and higher energy levels that the electrons disperse among orbitals more randomly and they need higher energy to be paired.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 22.7, Problem 22.5E

Interpretation Introduction

Interpretation:

Distribution of d-electrons in the complex ion [Ni(H2O)6]2+ has to be determined.

Concept Introduction:

The term Crystal field splitting refers to segregation of d-orbitals in to higher energy orbitals and lower energy orbitals when ligands approaches metal ion to co-ordinate. Crystal field splitting is said to be larger when the energy gap between higher energy d-orbitals and lower energy d-orbitals is larger. Crystal field splitting is said to be smaller when the energy gap between higher energy d-orbitals and lower energy d-orbitals is smaller.

Spectrochemical series refers to the arrangement of ligands with respect to crystal field splitting they cause in the d-orbitals of a metal ion. The ligand that causes larger splitting pattern is referred to as stronger ligand.

The ligands are arranged in increasing order of crystal field splitting they produce.

I−<Br−<S2−<SCN−<Cl−<NO3−<N3−<F−<OH−<C2O42−<H2O<NCS−<CH3CN<py<NH3<en<bipy<phen<NO2−<PPh3<CN−<CO

The ligand that causes larger crystal field splitting is strong ligand and the ligand that causes smaller splitting is termed as weak ligand.

Pairing energy refers to the energy required to pair the electrons - that is energy required to make two electrons to be paired in same orbital with opposite spins.

If the pairing energy of a complex is high it means the electrons are difficult to be paired and so the complex will be high spin complex with unpaired electrons. If the pairing energy of a complex is low it means the electrons are readily paired and so the complex will be low spin complex with paired electrons.

A complex with high splitting energy will have low pairing energy because high splitting energy indicates larger energy gap between lower and higher energy levels that the electrons need lesser energy to be paired and they tend to remain paired in lower energy orbitals. A complex with low splitting energy will have high pairing energy because low splitting energy indicates smaller energy gap between lower and higher energy levels that the electrons disperse among orbitals more randomly and they need higher energy to be paired.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 22.7, Problem 22.5E

Interpretation Introduction

Interpretation:

Distribution of d-electrons in the complex ion [Ni(H2O)6]2+ has to be determined.

Concept Introduction:

The term Crystal field splitting refers to segregation of d-orbitals in to higher energy orbitals and lower energy orbitals when ligands approaches metal ion to co-ordinate. Crystal field splitting is said to be larger when the energy gap between higher energy d-orbitals and lower energy d-orbitals is larger. Crystal field splitting is said to be smaller when the energy gap between higher energy d-orbitals and lower energy d-orbitals is smaller.

Spectrochemical series refers to the arrangement of ligands with respect to crystal field splitting they cause in the d-orbitals of a metal ion. The ligand that causes larger splitting pattern is referred to as stronger ligand.

The ligands are arranged in increasing order of crystal field splitting they produce.

I−<Br−<S2−<SCN−<Cl−<NO3−<N3−<F−<OH−<C2O42−<H2O<NCS−<CH3CN<py<NH3<en<bipy<phen<NO2−<PPh3<CN−<CO

The ligand that causes larger crystal field splitting is strong ligand and the ligand that causes smaller splitting is termed as weak ligand.

Pairing energy refers to the energy required to pair the electrons - that is energy required to make two electrons to be paired in same orbital with opposite spins.

If the pairing energy of a complex is high it means the electrons are difficult to be paired and so the complex will be high spin complex with unpaired electrons. If the pairing energy of a complex is low it means the electrons are readily paired and so the complex will be low spin complex with paired electrons.

A complex with high splitting energy will have low pairing energy because high splitting energy indicates larger energy gap between lower and higher energy levels that the electrons need lesser energy to be paired and they tend to remain paired in lower energy orbitals. A complex with low splitting energy will have high pairing energy because low splitting energy indicates smaller energy gap between lower and higher energy levels that the electrons disperse among orbitals more randomly and they need higher energy to be paired.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 22.7, Problem 22.5E

Interpretation Introduction

Interpretation:

Distribution of d-electrons in the complex ion [Ni(H2O)6]2+ has to be determined.

Concept Introduction:

The term Crystal field splitting refers to segregation of d-orbitals in to higher energy orbitals and lower energy orbitals when ligands approaches metal ion to co-ordinate. Crystal field splitting is said to be larger when the energy gap between higher energy d-orbitals and lower energy d-orbitals is larger. Crystal field splitting is said to be smaller when the energy gap between higher energy d-orbitals and lower energy d-orbitals is smaller.

Spectrochemical series refers to the arrangement of ligands with respect to crystal field splitting they cause in the d-orbitals of a metal ion. The ligand that causes larger splitting pattern is referred to as stronger ligand.

The ligands are arranged in increasing order of crystal field splitting they produce.

I−<Br−<S2−<SCN−<Cl−<NO3−<N3−<F−<OH−<C2O42−<H2O<NCS−<CH3CN<py<NH3<en<bipy<phen<NO2−<PPh3<CN−<CO

The ligand that causes larger crystal field splitting is strong ligand and the ligand that causes smaller splitting is termed as weak ligand.

Pairing energy refers to the energy required to pair the electrons - that is energy required to make two electrons to be paired in same orbital with opposite spins.

If the pairing energy of a complex is high it means the electrons are difficult to be paired and so the complex will be high spin complex with unpaired electrons. If the pairing energy of a complex is low it means the electrons are readily paired and so the complex will be low spin complex with paired electrons.

A complex with high splitting energy will have low pairing energy because high splitting energy indicates larger energy gap between lower and higher energy levels that the electrons need lesser energy to be paired and they tend to remain paired in lower energy orbitals. A complex with low splitting energy will have high pairing energy because low splitting energy indicates smaller energy gap between lower and higher energy levels that the electrons disperse among orbitals more randomly and they need higher energy to be paired.

Answer 6

Chapter 22.7, Problem 22.5E

Interpretation Introduction

Interpretation:

Distribution of d-electrons in the complex ion [Ni(H2O)6]2+ has to be determined.

Concept Introduction:

The term Crystal field splitting refers to segregation of d-orbitals in to higher energy orbitals and lower energy orbitals when ligands approaches metal ion to co-ordinate. Crystal field splitting is said to be larger when the energy gap between higher energy d-orbitals and lower energy d-orbitals is larger. Crystal field splitting is said to be smaller when the energy gap between higher energy d-orbitals and lower energy d-orbitals is smaller.

Spectrochemical series refers to the arrangement of ligands with respect to crystal field splitting they cause in the d-orbitals of a metal ion. The ligand that causes larger splitting pattern is referred to as stronger ligand.

The ligands are arranged in increasing order of crystal field splitting they produce.

I−<Br−<S2−<SCN−<Cl−<NO3−<N3−<F−<OH−<C2O42−<H2O<NCS−<CH3CN<py<NH3<en<bipy<phen<NO2−<PPh3<CN−<CO

The ligand that causes larger crystal field splitting is strong ligand and the ligand that causes smaller splitting is termed as weak ligand.

Pairing energy refers to the energy required to pair the electrons - that is energy required to make two electrons to be paired in same orbital with opposite spins.

If the pairing energy of a complex is high it means the electrons are difficult to be paired and so the complex will be high spin complex with unpaired electrons. If the pairing energy of a complex is low it means the electrons are readily paired and so the complex will be low spin complex with paired electrons.

A complex with high splitting energy will have low pairing energy because high splitting energy indicates larger energy gap between lower and higher energy levels that the electrons need lesser energy to be paired and they tend to remain paired in lower energy orbitals. A complex with low splitting energy will have high pairing energy because low splitting energy indicates smaller energy gap between lower and higher energy levels that the electrons disperse among orbitals more randomly and they need higher energy to be paired.

Answer 7

Chapter 22.7, Problem 22.5E

Interpretation Introduction

Interpretation:

Distribution of d-electrons in the complex ion [Ni(H2O)6]2+ has to be determined.

Concept Introduction:

The term Crystal field splitting refers to segregation of d-orbitals in to higher energy orbitals and lower energy orbitals when ligands approaches metal ion to co-ordinate. Crystal field splitting is said to be larger when the energy gap between higher energy d-orbitals and lower energy d-orbitals is larger. Crystal field splitting is said to be smaller when the energy gap between higher energy d-orbitals and lower energy d-orbitals is smaller.

Spectrochemical series refers to the arrangement of ligands with respect to crystal field splitting they cause in the d-orbitals of a metal ion. The ligand that causes larger splitting pattern is referred to as stronger ligand.

The ligands are arranged in increasing order of crystal field splitting they produce.

I−<Br−<S2−<SCN−<Cl−<NO3−<N3−<F−<OH−<C2O42−<H2O<NCS−<CH3CN<py<NH3<en<bipy<phen<NO2−<PPh3<CN−<CO

The ligand that causes larger crystal field splitting is strong ligand and the ligand that causes smaller splitting is termed as weak ligand.

Pairing energy refers to the energy required to pair the electrons - that is energy required to make two electrons to be paired in same orbital with opposite spins.

If the pairing energy of a complex is high it means the electrons are difficult to be paired and so the complex will be high spin complex with unpaired electrons. If the pairing energy of a complex is low it means the electrons are readily paired and so the complex will be low spin complex with paired electrons.

A complex with high splitting energy will have low pairing energy because high splitting energy indicates larger energy gap between lower and higher energy levels that the electrons need lesser energy to be paired and they tend to remain paired in lower energy orbitals. A complex with low splitting energy will have high pairing energy because low splitting energy indicates smaller energy gap between lower and higher energy levels that the electrons disperse among orbitals more randomly and they need higher energy to be paired.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Concept explainers

Want to see the full answer?

Chapter 22 Solutions