The amino acids that have more than one asymmetric center has to be given. Concept Introduction: Configuration of Amino Acids: In a Fischer projection, with the carbonyl group at the top and the R group at the bottom of the vertical axis and the amino group is on the right side is a D-amino acid; with the carbonyl group at the top and the R group at the bottom of the vertical axis and the amino group is on the left side is L-amino acid. Rules for assigning (R, S) - configuration: 1. Prioritize the four groups around the chiral center according to atomic number . 2. Orient the chiral center such that the least priority substituent is pointing away from the viewer. 3. Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

Question

Want to see the full answer?

Answer 1

Question

Chapter 22.2, Problem 4P

Interpretation Introduction

Interpretation:

The amino acids that have more than one asymmetric center has to be given.

Concept Introduction:

Configuration of Amino Acids:

In a Fischer projection, with the carbonyl group at the top and the R group at the bottom of the vertical axis and the amino group is on the right side is a D-amino acid; with the carbonyl group at the top and the R group at the bottom of the vertical axis and the amino group is on the left side is L-amino acid.

Rules for assigning (R, S) - configuration:

1. Prioritize the four groups around the chiral center according to atomic number.

2. Orient the chiral center such that the least priority substituent is pointing away from the viewer.

3. Trace the path of priorities; is the path traced is clockwise, the chiral center is assigned as R. If the path is traced in anti-clockwise, the chiral center is assigned as S.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

a) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if applicable). ード M 4- b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible isomers and their corresponding point groups. Use the point groups to determine if the complexes have resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if applicable). The number of complex sketches below is not necessarily indicative of the number of isomers. 4- 4- ☐☐☐ c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible isomers and their corresponding point groups.. Use the point groups to determine if the complexes have resulting net dipole…

Show work. don't give Ai generated solution

Differentiate electron spin and electron spin moment.