For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names. Concept Introduction: If , and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively. There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given. The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes . If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent. If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result. If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

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Chapter 22.2, Problem 2PTS

(a)

Interpretation Introduction

Interpretation:

For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

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Experiment 1 Data Table 1: Conservation of Mass - Initial Mass Data Table 1 Data Table 2 Data Table 3 Data Table 4 Panel 1 Photo 1 Data Table 5 Reaction Mass of test tube and 5.0% HC₂H₂O2 (g) # (A) (B) Mass of NaHCO, (g) Mass of balloon and NaHCO, (g) (C) 0.10 1 0829 14.38g 0.20 2 0.929 14.29g 0.35 1.00g 3 14.25g 0.50 1.14g 14.29 Experiment 1 Data Table 2: Moles of HC2H3O2 Reaction Volume of Mass of Moles of HC₂H₂O₂ 5.0% Vinegar (g) (ML) 5.0 0.25 0042 mol 2 5.0 0.25 0042 mol 3 5.0 0.25 0042 mol 5.0 0.25 0042 mol Experiment 1 Data Table 3: Moles of NaHCO3 Reaction Mass of NaHCO (g) 10g 20g 35g 50g Experiment 1 Data Table 4: Theoretical Yield of CO₂ Reaction # 1 2 3 Experiment 1 Total mass before reaction (g) (D=A+C) 15.29 15.21g 15.25g 15.349 Exercise 1 Data Table 1 Data Table 2 Data Table 3 Data Table 4 Panel 1 Photo 1 Data Table 5 Exercise 1- Data Table 1 Data Table 2 DataTable 3 Data Table 4 Panel 1 Photo 1 Data Table 5 Exercise 1- Moles of NaHCO 0012 mol 0025 mol 0044 mol 0062 mol…

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Answer 2

Question

Chapter 22.2, Problem 2PTS

(a)

Interpretation Introduction

Interpretation:

For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

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Answer 3

Question

Chapter 22.2, Problem 2PTS

(a)

Interpretation Introduction

Interpretation:

For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

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Answer 4

Question

Chapter 22.2, Problem 2PTS

(a)

Interpretation Introduction

Interpretation:

For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

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Answer 5

Chapter 22.2, Problem 2PTS

(a)

Interpretation Introduction

Interpretation:

For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 6

Chapter 22.2, Problem 2PTS

(a)

Interpretation Introduction

Interpretation:

For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 7

Chapter 22.2, Problem 2PTS

(a)

Interpretation Introduction

Interpretation:

For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 8

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 9

(b)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 10

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 11

(c)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 12

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 13

(d)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 14

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 15

(e)

Interpretation Introduction

Interpretation: For a given set of nitrogen containing compounds, the structures have to be drawn using their general or IUPAC names.

Concept Introduction: If, and groups are attached to the parent carbon, they are called primary, secondary and tertiary amines respectively.

There are two ways followed to name the compound. First one is the method of giving general name in which name of the alkyl group followed by amine name is given. Second one is the method giving IUPAC name in which name of the alkane group followed by amine name is given.

The length of the chain which is having more number of carbon atoms is selected as the parent or main chain. Other chains are considered as substituents to the main chain. Position of the substituents should be included in the name. If one, two, three, four, five, six, etc carbons are activating as the main chain in IUPAC system, then the name of the compound comes as methane, ethane, propane, butane, pentane, hexane, etc. which are the name of alkanes. If one, two, three, four, five, six, etc carbons are activating as the main chain in general name method, then the name of the compound comes as methyl, ethyl, propyl, butyl, pentyl, hexyl, etc. which are the name of alkyl groups. If substituent groups are attached to nitrogen atom as in the case of tertiary or secondary amines, the name is given as N-alkyl name of the substituent.

If any configuration is present in the compound, that should be assigned to it while writing the name. If the compound contains heavier groups on the same side, it gets (Z)-configuration. If they are on the opposite directions, (E)-configurations result.

If a carbon has four different groups attached to it, that carbon shows a chirality nature. If that chiral carbon rotates the plane polarized light into a clockwise direction, it gets (R)-isomer. If that carbon rotates the plane polarized light into a counter-clockwise direction, it gets (S)-isomer.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 22.2 - Prob. 1LTS Ch. 22.2 - Prob. 1PTS Ch. 22.2 - Prob. 2PTS Ch. 22.2 - Prob. 3ATS Ch. 22.3 - Prob. 4CC Ch. 22.3 - Prob. 5CC Ch. 22.3 - Prob. 6CC Ch. 22.3 - Prob. 7CC Ch. 22.3 - Prob. 8CC Ch. 22.3 - Prob. 9CC

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Chapter 22 Solutions