The synthesis of the given product from suitable Michael donor and acceptor. Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized. Concept introduction: When the double bond of an α , β − unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α , β − unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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Answer 1

Question

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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(EXM 2, PRBLM 3) Here is this problem, can you explain it to me and show how its done. Thank you I need to see the work for like prbl solving.

can someone draw out the reaction mechanism for this reaction showing all bonds, intermediates and side products Comment on the general features of the 1H-NMR spectrum of isoamyl ester provided below

What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.

Answer 2

Question

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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Answer 3

Question

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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Answer 4

Question

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

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Answer 5

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 6

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 7

Chapter 22.18, Problem 22.56P

(a)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 8

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 9

(b)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 10

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 11

(c)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 12

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 13

(d)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 14

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 15

(e)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 16

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 17

(f)

Interpretation Introduction

To determine: The synthesis of the given product from suitable Michael donor and acceptor.

Interpretation: The given product from suitable Michael donor and acceptor is to be synthesized.

Concept introduction: When the double bond of an α,β− unsaturated carbonyl compound or any other electron-poor double bond undergoes conjugate addition through carbanion, the reaction is called as Michael addition. The electrophile or an α,β− unsaturated carbonyl compound accepts a pair of electrons and called as the Michael acceptor. The attacking nucleophile that donates a pair of electrons is called as the Michael donor.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 22.2A - Prob. 22.2P Ch. 22.4 - Without looking back, propose a mechanism for the...Ch. 22.4 - Prob. 22.8P Ch. 22.4 - Prob. 22.9P Ch. 22.5A - Prob. 22.10P Ch. 22.5A - Prob. 22.11P Ch. 22.5B - Prob. 22.12P Ch. 22.5B - Predict the products of the following reactions....Ch. 22.5B - Which compounds will give positive iodoform tests?...Ch. 22.5C - Propose a mechanism for the acid-catalyzed...

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Chapter 22 Solutions