The method for the synthesis of given ketone has to be stated with the help of acetoacetic ester synthesis. Concept introduction: The final products of acetoacetic ester synthesis are ketones , specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22.17, Problem 22.50P

(a)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone has to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(b)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(c)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22.17, Problem 22.50P

(a)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone has to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(b)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(c)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22.17, Problem 22.50P

(a)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone has to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(b)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(c)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22.17, Problem 22.50P

(a)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone has to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(b)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(c)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

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Answer 5

Chapter 22.17, Problem 22.50P

(a)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone has to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(b)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

(c)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

Answer 6

Chapter 22.17, Problem 22.50P

(a)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone has to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

Answer 7

Chapter 22.17, Problem 22.50P

(a)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone has to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The method for the synthesis of given ketone is to be stated with the help of acetoacetic ester synthesis.

Concept introduction:

The final products of acetoacetic ester synthesis are ketones, specially substituted derivatives of acetone. In acetoacetic ester synthesis, substituents are added to the enolate ion of acetoacetic ester. Then, hydrolysis takes place followed by decarboxylation to give alkylated derivatives of acetone.

Answer 12

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Answer 15

Ch. 22.2A - Prob. 22.2P Ch. 22.4 - Without looking back, propose a mechanism for the...Ch. 22.4 - Prob. 22.8P Ch. 22.4 - Prob. 22.9P Ch. 22.5A - Prob. 22.10P Ch. 22.5A - Prob. 22.11P Ch. 22.5B - Prob. 22.12P Ch. 22.5B - Predict the products of the following reactions....Ch. 22.5B - Which compounds will give positive iodoform tests?...Ch. 22.5C - Propose a mechanism for the acid-catalyzed...

Solution Summary: The author explains that the method for the synthesis of given ketone is to be stated with the help of acetoacetic ester.

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