a) Interpretation: The enol tautomer of Cyclopentanone shown is to be given. Concept introduction: A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers. To give: The enol tautomer of cyclopentanone shown.

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Answer 1

Question

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

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Dr. Mendel asked his BIOL 260 class what their height was and what their parent's heights were. He plotted that data in the graph below to determine if height was a heritable trait. A. Is height a heritable trait? If yes, what is the heritability value? (2 pts) B. If the phenotypic variation is 30, what is the variation due to additive alleles? (2 pts) Offspring Height (Inches) 75 67.5 60 52.5 y = 0.9264x + 4.8519 55 60 65 MidParent Height (Inches) 70 75 12pt v V Paragraph B IUA > AT2 v V

Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

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Answer 3

Question

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

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Answer 4

Question

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

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Answer 5

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

Answer 6

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Answer 7

Chapter 22.1, Problem 1P

Interpretation Introduction

a)

Interpretation:

The enol tautomer of Cyclopentanone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of cyclopentanone shown.

Answer 8

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Answer 9

Interpretation Introduction

b)

Interpretation:

The enol tautomer of Methyl thioacetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Methyl thioacetate shown.

Answer 10

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Answer 11

Interpretation Introduction

c)

Interpretation:

The enol tautomer of Ethyl acetate shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Ethyl acetate shown.

Answer 12

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Answer 13

Interpretation Introduction

d)

Interpretation:

The enol tautomer of Propanal shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Propanal shown.

Answer 14

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Answer 15

Interpretation Introduction

e)

Interpretation:

The enol tautomer of Acetic acid shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Acetic acid shown.

Answer 16

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

Answer 17

Interpretation Introduction

f)

Interpretation:

The enol tautomer of Phenylacetone shown is to be given.

Concept introduction:

A carbonyl compound with a hydrogen atom on its α carbon atom is in equilibrium with its corresponding enol isomer. The spontaneous inter-conversion between two isomers usually with the change in position of a hydrogen is called tautomerism. The individual keto and enol isomers are called tautomers.

To give:

The enol tautomer of Phenylaceton shown.

Answer 18

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Ch. 22.1 - Prob. 1P Ch. 22.1 - How many acidic hydrogens does each of the...Ch. 22.1 - Prob. 3P Ch. 22.3 - Write the complete mechanism for the deuteration...Ch. 22.3 - Prob. 5P Ch. 22.4 - If methanol rather than water is added at the end...Ch. 22.5 - Prob. 7P Ch. 22.5 - Draw a resonance structure of the acetonitrile...Ch. 22.6 - If methanol rather than water is added at the end...Ch. 22.7 - Prob. 10P

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