Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 2.21, Problem 15P
Match the boiling points with the appropriate
Alkanes: octane,
Boiling points (°C,
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The melting points and boiling points of two isomeric alkanes are asfollows: CH3(CH2)6CH3, mp = −57 °C and bp = 126 °C; (CH3)3CC(CH3)3,mp = 102 °C and bp = 106 °C.
Explain why one isomer has a lower melting point but higher boiling point.
Arrange the following compounds in order of decreasing heat of combustion: pentane, 2-methylbutane, 2,2-dimethylpropane, hexane.
What alkane, with molecular formula C5H12, forms only one monochlorinated product when it is heated with Cl2?
Chapter 2 Solutions
Organic Chemistry - Standalone book
Ch. 2.4 - Prob. 1PCh. 2.7 - Prob. 2PCh. 2.8 - Identify the orbital overlaps of all of the bonds...Ch. 2.9 - The hydrocarbon shown, called vinylacetylene, is...Ch. 2.12 - Prob. 5PCh. 2.12 - Prob. 6PCh. 2.13 - Prob. 7PCh. 2.14 - Refer to Table 2.2 as needed to answer the...Ch. 2.15 - Prob. 9PCh. 2.15 - Prob. 10P
Ch. 2.16 - Prob. 11PCh. 2.17 - Prob. 12PCh. 2.18 - Prob. 13PCh. 2.20 - Prob. 14PCh. 2.21 - Match the boiling points with the appropriate...Ch. 2.22 - Write a balanced chemical equation for the...Ch. 2.22 - Using the data in Table 2.3, estimate the heat of...Ch. 2.22 - Prob. 18PCh. 2.22 - Prob. 19PCh. 2.23 - Prob. 20PCh. 2.23 - Which of the following reactions requires an...Ch. 2 - The general molecular formula for alkanes is...Ch. 2 - Prob. 23PCh. 2 - Prob. 24PCh. 2 - Prob. 25PCh. 2 - What is the hybridization of each carbon in...Ch. 2 - Prob. 27PCh. 2 - Does the overlap of two p orbitals in the fashion...Ch. 2 - Prob. 29PCh. 2 - Aphids secrete an alarm pheromone having the...Ch. 2 - All the parts of this problem refer to the alkane...Ch. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - From among the 18 constitutional isomers of C8H18,...Ch. 2 - Give the IUPAC name for each of the following...Ch. 2 - Using the method outlined in Section 2.16, give an...Ch. 2 - Prob. 38PCh. 2 - Write a balanced chemical equation for the...Ch. 2 - The heats of combustion of methane and butane are...Ch. 2 - In each of the following groups of compounds,...Ch. 2 - Given H for the reaction H2(g)+12O2(g)H2O(l)...Ch. 2 - Prob. 43PCh. 2 - Prob. 44PCh. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Compound A undergoes the following reactions:...Ch. 2 - Prob. 49PCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 51DSPCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 53DSP
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- Define Acyclic Alkanes Having One to Five C Atoms ?arrow_forwardExplain Acyclic Alkanes Having More Than Five C Atoms ?arrow_forwarddraw structural formulas for all isomeric alkanes with molecular formula C7H16. Predict which isomer has the lowest boiling point and which has the highest boiling point.arrow_forward
- What is the structure of a compound with the formula C7H14O that has an ether and cyclobutane ring, including its IUPAC name? In addition, what is the structure of the compound with the formula C7H14O that does NOT contain the functional groups: epoxide, ether, cycloalkane, alcohol, alkene. Indicate the functional groups used that are present in the structure made for this compound.arrow_forwardDraw all possible structure(s) and give the IUPAC systematic name(s) of an alkane or cycloalkane with the formula C8H18 that has only primary hydrogen atoms. Draw the structure(s).arrow_forwardA student was given the following list of structural formulas of several compounds and was asked to give them systematic names. How many did the student name correctly? Correct those that are misnamed and explain why it is incorrect. 2,2-dimethyl-4-ethylheptane 5-(2,2-dimethylethyl)nonane 3,3-dichlorooctane 5-ethyl-2-methylhexane 3-isopropyloctane 2-methyl-2-isopropylheptanearrow_forward
- What is a structure for a compound that is an eight-carbon alkane, serves as the 100 octane standard for gasoline. It has five methyl groups, one quaternary carbon, tests negative for C-C double bonds and gives four monochloro substitution products, C8H17Cl.arrow_forward1. Write the specific structural formula asked and the type of aliphatic hydrocarbon (alkane, cycloalkane, alkene, cycloalkene, alkyne) of the following organic compounds: 1. 2-ethyl-1,1,3,3-tetramethylcyclopentane • Extended structural formula • Line structural formula • Type of hydrocarbon 2. trans-4-methyl-2-hexene • Condensed structural formula Line structural formula Type of hydrocarbon 3. 2,4-dibromo-5-ethyloctane • Extended structural formula • Condensed structural formula Type of hydrocarbon 4. 4-methyl-2-hexyne • Extended structural formula • Line structural formula Type of hydrocarbon 5. 3,3-dimethylcyclohexene • Condensed structural formula • Line structural formula Type of hydrocarbonarrow_forwardGive the systematic names for all alkanes with molecular formula C7H16 that do not have any secondary hydrogens.arrow_forward
- The name of an alkyne that has 7 carbon atoms (C1C2C3C4C5C6C7) where the carbon - carbon triple bond is between carbon 5 and 6; and with 2 methyl substituent located at C 3 and C 4 is ____.arrow_forwardExplain why alkenes are much more reactive than alkanes towards chlorine (CI2) or bromine (Br2) in the dark at room temperature, and why alkanes do not react with HCI (g) or HBr (g) whereas alkenes do.arrow_forwardI am confused as to which compound from the following: cyclhexane, ethyne, hept-2-ene, Ch2(CH2)14Ch2OH, dode-1-yne, Ch3Ch2CO2H,Propan-2-ol, Ch3(Ch2)14CO2H; is miscible in water, is an insoluble gas, is a water insosuble solid, is a wter insoluble liquid, is a water insoluble liquid- it burns clean, is a water insuloble liquid-it burns dirty, us water mscible. What do I look for to assign each compound to its coorect characterisitcs.arrow_forward
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