Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 2.21, Problem 15P
Match the boiling points with the appropriate
Alkanes: octane,
Boiling points (°C,
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The melting points and boiling points of two isomeric alkanes are asfollows: CH3(CH2)6CH3, mp = −57 °C and bp = 126 °C; (CH3)3CC(CH3)3,mp = 102 °C and bp = 106 °C.
Explain why one isomer has a lower melting point but higher boiling point.
Arrange the following compounds in order of decreasing heat of combustion: pentane, 2-methylbutane, 2,2-dimethylpropane, hexane.
What alkane, with molecular formula C5H12, forms only one monochlorinated product when it is heated with Cl2?
Chapter 2 Solutions
Organic Chemistry - Standalone book
Ch. 2.4 - Prob. 1PCh. 2.7 - Prob. 2PCh. 2.8 - Identify the orbital overlaps of all of the bonds...Ch. 2.9 - The hydrocarbon shown, called vinylacetylene, is...Ch. 2.12 - Prob. 5PCh. 2.12 - Prob. 6PCh. 2.13 - Prob. 7PCh. 2.14 - Refer to Table 2.2 as needed to answer the...Ch. 2.15 - Prob. 9PCh. 2.15 - Prob. 10P
Ch. 2.16 - Prob. 11PCh. 2.17 - Prob. 12PCh. 2.18 - Prob. 13PCh. 2.20 - Prob. 14PCh. 2.21 - Match the boiling points with the appropriate...Ch. 2.22 - Write a balanced chemical equation for the...Ch. 2.22 - Using the data in Table 2.3, estimate the heat of...Ch. 2.22 - Prob. 18PCh. 2.22 - Prob. 19PCh. 2.23 - Prob. 20PCh. 2.23 - Which of the following reactions requires an...Ch. 2 - The general molecular formula for alkanes is...Ch. 2 - Prob. 23PCh. 2 - Prob. 24PCh. 2 - Prob. 25PCh. 2 - What is the hybridization of each carbon in...Ch. 2 - Prob. 27PCh. 2 - Does the overlap of two p orbitals in the fashion...Ch. 2 - Prob. 29PCh. 2 - Aphids secrete an alarm pheromone having the...Ch. 2 - All the parts of this problem refer to the alkane...Ch. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - From among the 18 constitutional isomers of C8H18,...Ch. 2 - Give the IUPAC name for each of the following...Ch. 2 - Using the method outlined in Section 2.16, give an...Ch. 2 - Prob. 38PCh. 2 - Write a balanced chemical equation for the...Ch. 2 - The heats of combustion of methane and butane are...Ch. 2 - In each of the following groups of compounds,...Ch. 2 - Given H for the reaction H2(g)+12O2(g)H2O(l)...Ch. 2 - Prob. 43PCh. 2 - Prob. 44PCh. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Compound A undergoes the following reactions:...Ch. 2 - Prob. 49PCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 51DSPCh. 2 - Some Biochemical Reactions of Alkanes Alkanes...Ch. 2 - Prob. 53DSP
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- Both olives and the leaves of olive trees contain alkanes with long carbon chains. A predominant alkane in olives has 27 carbons, whereas a major alkane component in olive leaves has 31 carbons. What is the molecular formula of each of these alkanes?arrow_forwardDefine Acyclic Alkanes Having One to Five C Atoms ?arrow_forwardExplain Acyclic Alkanes Having More Than Five C Atoms ?arrow_forward
- draw structural formulas for all isomeric alkanes with molecular formula C7H16. Predict which isomer has the lowest boiling point and which has the highest boiling point.arrow_forwardDraw all possible structure(s) and give the IUPAC systematic name(s) of an alkane or cycloalkane with the formula C8H18 that has only primary hydrogen atoms. Draw the structure(s).arrow_forwardWhat is a structure for a compound that is an eight-carbon alkane, serves as the 100 octane standard for gasoline. It has five methyl groups, one quaternary carbon, tests negative for C-C double bonds and gives four monochloro substitution products, C8H17Cl.arrow_forward
- Give the systematic names for all alkanes with molecular formula C7H16 that do not have any secondary hydrogens.arrow_forwardExplain why alkenes are much more reactive than alkanes towards chlorine (CI2) or bromine (Br2) in the dark at room temperature, and why alkanes do not react with HCI (g) or HBr (g) whereas alkenes do.arrow_forwardI am confused as to which compound from the following: cyclhexane, ethyne, hept-2-ene, Ch2(CH2)14Ch2OH, dode-1-yne, Ch3Ch2CO2H,Propan-2-ol, Ch3(Ch2)14CO2H; is miscible in water, is an insoluble gas, is a water insosuble solid, is a wter insoluble liquid, is a water insoluble liquid- it burns clean, is a water insuloble liquid-it burns dirty, us water mscible. What do I look for to assign each compound to its coorect characterisitcs.arrow_forward
- Indicate whether each statement is true or false. Alkanes do not have any carbon-carbon multiple bonds. Cyclobutane contains a four-membered ring. Alkenes contain carbon-carbon triple bonds. Alkynes contain carbon-carbon double bonds. Pentene is a saturated hydrocarbon. 1-pentene is an unsaturated hydrocarbon. Cyclohexane is an aromatic hydrocarbon. The methyl group contains one less hydrogen atom than methane.arrow_forwardName each of the following cyclic alkanes, and indicate the formula of the compound.arrow_forwardexplain structural isomerism in aliphatic alkanes and geometric isomerism in alkenes. Describe structural isomerism and the different types that exist. With the aid of diagrams use the molecular formulae C5H12 and C5H10 to explain structural isomerism in aliphatic alkanes and alkenes. Describe geometric isomerism. With the aid of diagrams use the molecular formula C5H10 to explain geometric isomerism in alkenes.arrow_forward
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