OWLv2 6-Months Printed Access Card for Kotz/Treichel/Townsend's Chemistry & Chemical Reactivity, 9th, 9th Edition
OWLv2 6-Months Printed Access Card for Kotz/Treichel/Townsend's Chemistry & Chemical Reactivity, 9th, 9th Edition
9th Edition
ISBN: 9781285460680
Author: Kotz, Treichel, Townsend
Publisher: Cengage Learning
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Chapter 22, Problem 71GQ
Interpretation Introduction

Interpretation: The structure of three isomers has to be drawn and chirality has to be predicted.

Concept introduction:

Formula of coordination compounds: Formula of a coordination complex is able to predict by using the metal ion and ligands, and to derive the oxidation number of the coordinated metal ion.

Isomerism: Isomers are compounds with same molecular formula with different arrangements of atoms.

  • Structural isomers:  have same molecular formula but different bonding arrangements of atoms. It is classified into coordination isomer (occurs by exchanging a coordinated ligand and the counter-ions) and linkage isomers (ligand attached through different atoms to the metal).
  • Stereoisomers: differ in their spatial arrangement of atoms.

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Q2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol‍¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.

Chapter 22 Solutions

OWLv2 6-Months Printed Access Card for Kotz/Treichel/Townsend's Chemistry & Chemical Reactivity, 9th, 9th Edition

Ch. 22.7 - Prob. 2.2ACPCh. 22.7 - How are the d electrons of Pt distributed in a...Ch. 22.7 - What are the electron configurations for Nd and...Ch. 22.7 - Prob. 3.2ACPCh. 22.7 - Prob. 3.3ACPCh. 22.7 - Prob. 3.4ACPCh. 22 - Identify, based on the position in the periodic...Ch. 22 - Prob. 2PSCh. 22 - Prob. 3PSCh. 22 - Prob. 4PSCh. 22 - Prob. 5PSCh. 22 - Iron is the most abundant transition element in...Ch. 22 - Prob. 7PSCh. 22 - Prob. 8PSCh. 22 - Prob. 9PSCh. 22 - Prob. 10PSCh. 22 - Identify a cation of a first series transition...Ch. 22 - Match up the isoelectronic ions on the following...Ch. 22 - The lanthanide contraction is given as an...Ch. 22 - Prob. 14PSCh. 22 - Prob. 15PSCh. 22 - Prob. 16PSCh. 22 - Prob. 17PSCh. 22 - Prob. 18PSCh. 22 - Which of the following ligands is expected to be...Ch. 22 - One of the following nitrogen compounds or ions is...Ch. 22 - Prob. 21PSCh. 22 - Prob. 22PSCh. 22 - Prob. 23PSCh. 22 - Prob. 24PSCh. 22 - Prob. 25PSCh. 22 - Prob. 26PSCh. 22 - Prob. 27PSCh. 22 - Prob. 28PSCh. 22 - Prob. 29PSCh. 22 - Prob. 30PSCh. 22 - Give the name or formula for each ion or compound,...Ch. 22 - Prob. 32PSCh. 22 - Prob. 33PSCh. 22 - Prob. 34PSCh. 22 - Prob. 35PSCh. 22 - Prob. 36PSCh. 22 - Prob. 37PSCh. 22 - Prob. 38PSCh. 22 - Prob. 39PSCh. 22 - Prob. 40PSCh. 22 - Prob. 41PSCh. 22 - Prob. 42PSCh. 22 - Prob. 43PSCh. 22 - Prob. 44PSCh. 22 - Prob. 45PSCh. 22 - Prob. 46PSCh. 22 - Prob. 47PSCh. 22 - Prob. 48PSCh. 22 - Prob. 49PSCh. 22 - Prob. 50PSCh. 22 - In water, the titanium(III) ion, [Ti(H2O)6]3+, has...Ch. 22 - Prob. 52PSCh. 22 - Prob. 53GQCh. 22 - Prob. 54GQCh. 22 - How many unpaired electrons are expected for...Ch. 22 - Prob. 56GQCh. 22 - Which of the following complex ions is (are)...Ch. 22 - Prob. 58GQCh. 22 - How many geometric isomers are possible for the...Ch. 22 - For a tetrahedral complex of a metal in the first...Ch. 22 - Prob. 61GQCh. 22 - Prob. 62GQCh. 22 - Prob. 63GQCh. 22 - A platinum-containing compound, known as Magnuss...Ch. 22 - Prob. 65GQCh. 22 - Prob. 66GQCh. 22 - Prob. 67GQCh. 22 - How many geometric isomers of the complex ion...Ch. 22 - Prob. 69GQCh. 22 - Prob. 70GQCh. 22 - Prob. 71GQCh. 22 - The square-planar complex Pt(en)Cl2 has chloride...Ch. 22 - The complex [Mn(H2O)6]2+ has five unpaired...Ch. 22 - Experiments show that K4[Cr(CN)6] is paramagnetic...Ch. 22 - Give a systematic name or the formula for the...Ch. 22 - When CrCI3 dissolves in water, three different...Ch. 22 - Prob. 77GQCh. 22 - The glycinate ion, H2NCH2CO2, formed by...Ch. 22 - Prob. 79GQCh. 22 - Nickel and palladium both form complexes of the...Ch. 22 - The transition metals form a class of compounds...Ch. 22 - Cerium, as noted in Applying Chemical Principles:...Ch. 22 - Prob. 84GQCh. 22 - Two different coordination compounds containing...Ch. 22 - Prob. 89SCQCh. 22 - Prob. 90SCQ
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