(a) To determine: Square planar [NiWXYZ] 2+ is optically active or not where W,X,Y and Z are monodentate ligands

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Answer 1

Question

Chapter 22, Problem 64E

Interpretation Introduction

(a)

To determine:

Square planar [NiWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Interpretation Introduction

(b)

To determine:

Tetrahedral [ZnWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

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eks.com/aleksogi/x/sl.exe/1o_u-IgNslkr7j8P3jH-IQs_pBanHhvTCeeBZbufuBYTI0Hz7m7D3ZS17Hd6m-HIl6n52njJN-TXdQA2X9yID-1SWQJTgnjARg30 111 States of Matter Understanding conceptual components of the enthalpy of solution 0/5 Ge A small amount of acetonitrile (CH, CN) is dissolved in a large amount of water. Imagine separating this process into the four stages sketched below. (These sketches show only a portion of the substances, so you can see the density and distribution of atoms and molecules in them.) CH,CN H₂O B 88 C Use these sketches to answer the questions in the table below. The enthalpy of solution AH is negative soln when CH3CN dissolves in water. Use this information to list the stages in order of increasing enthalpy. Would heat be absorbed or released if the system moved from Stage C to D? What force would oppose or favor the system moving from Stage C to D? Check all that apply. 1 absorbed O released neither absorbed nor released. none O ionic bonding force covalent bonding force…

In a system with an anodic overpotential, the variation of ŋ as a function of the current density: 1. at low fields is linear 2. at higher fields, it follows Tafel's law Find the range of current densities for which the overpotential has the same value as when calculated for cases 1 and 2 (maximum relative difference of 5% with respect to the behavior for higher fields). To which overpotential range does this correspond? Data: 10 = 1.5 mA cm², T = 300°C, ẞ = 0.64, R = 8.314 J K 1 mol‍¹ and F = 96485 C mol-1.

Indicate 10.6 with only one significant figure.

Answer 2

Question

Chapter 22, Problem 64E

Interpretation Introduction

(a)

To determine:

Square planar [NiWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Interpretation Introduction

(b)

To determine:

Tetrahedral [ZnWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 22, Problem 64E

Interpretation Introduction

(a)

To determine:

Square planar [NiWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Interpretation Introduction

(b)

To determine:

Tetrahedral [ZnWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 22, Problem 64E

Interpretation Introduction

(a)

To determine:

Square planar [NiWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Interpretation Introduction

(b)

To determine:

Tetrahedral [ZnWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 22, Problem 64E

Interpretation Introduction

(a)

To determine:

Square planar [NiWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Interpretation Introduction

(b)

To determine:

Tetrahedral [ZnWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Answer 6

Chapter 22, Problem 64E

Interpretation Introduction

(a)

To determine:

Square planar [NiWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Answer 7

Chapter 22, Problem 64E

Interpretation Introduction

(a)

To determine:

Square planar [NiWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Answer 8

Interpretation Introduction

(b)

To determine:

Tetrahedral [ZnWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Answer 9

Interpretation Introduction

(b)

To determine:

Tetrahedral [ZnWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

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Answer 13

Ch. 22 - When a transition metal atom forms an ion, which...Ch. 22 - Explain why transition metals exhibit multiple...Ch. 22 - Why is the +2 oxidation state so common for...Ch. 22 - Explain why atomic radii of elements in the third...Ch. 22 - Gold is the most electronegative transition metal....Ch. 22 - Prob. 6E Ch. 22 - Prob. 7E Ch. 22 - Explain the differences between each pair of...Ch. 22 - Prob. 9E Ch. 22 - Prob. 10E

(a) To determine: Square planar [NiWXYZ] 2+ is optically active or not where W,X,Y and Z are monodentate ligands

Solution Summary: The author explains that square planar complexes have all ligands on the same plane to that of central metal, which results in symmetry and causes the optical inactivity.

Concept explainers

(a)

To determine:

Square planar [NiWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

(b)

To determine:

Tetrahedral [ZnWXYZ]²⁺ is optically active or not where W,X,Y and Z are monodentate ligands

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Chapter 22 Solutions

(a) To determine: Square planar [NiWXYZ] 2+ is optically active or not where W,X,Y and Z are monodentate ligands

Solution Summary: The author explains that square planar complexes have all ligands on the same plane to that of central metal, which results in symmetry and causes the optical inactivity.

Concept explainers