(a) Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown. Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β − carbon of the other α , β − unsaturated carbonyl compound is known as Michael reaction. The α , β − unsaturated carbonyl compounds are also called as Michael acceptors.

Question

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Answer 1

Question

Chapter 22, Problem 44P

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

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Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 22, Problem 44P

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

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Answer 3

Question

Chapter 22, Problem 44P

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

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Answer 4

Question

Chapter 22, Problem 44P

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

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Answer 5

Chapter 22, Problem 44P

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 6

Chapter 22, Problem 44P

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 7

Chapter 22, Problem 44P

Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 8

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 9

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 10

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 11

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to prepare the given compound by a Michael reaction are to be shown.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 12

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Answer 23

Ch. 22.1 - Prob. 1P Ch. 22.1 - Prob. 2P Ch. 22.1 - Problem 24.3 What unsaturated carbonyl compound is...Ch. 22.1 - Prob. 4P Ch. 22.1 - Prob. 5P Ch. 22.2 - Prob. 6P Ch. 22.2 - Problem 24.7 Draw the products formed in each...Ch. 22.4 - Prob. 15P Ch. 22.4 - Prob. 16P Ch. 22.5 - Problem 24.16 What ester is formed when each...

Solution Summary: The author explains the starting materials that are needed to prepare the given compound by a Michael reaction.

Chapter 22 Solutions