(a) Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using − OH , H 2 O is to be drawn. Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry . In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β -hydroxyaldehyde or β -hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 1

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Chapter 22, Problem 31P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 22, Problem 31P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 3

Question

Chapter 22, Problem 31P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 4

Question

Chapter 22, Problem 31P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

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Answer 5

Chapter 22, Problem 31P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 6

Chapter 22, Problem 31P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 7

Chapter 22, Problem 31P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 10

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 11

Interpretation Introduction

(c)

Interpretation: The product that is formed by the aldol reaction of the given starting material(s) by using −OH, H2O is to be drawn.

Concept introduction: Aldol reaction is the condensation reaction of the organic chemistry. In this reaction an enolate ion or an enol reacts with the carbonyl compound that leads to the formation of β-hydroxyaldehyde or β-hydroxyketone which on further dehydration gives the conjugated enone.

Answer 12

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Answer 14

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Answer 15

Ch. 22.1 - Prob. 1P Ch. 22.1 - Prob. 2P Ch. 22.1 - Problem 24.3 What unsaturated carbonyl compound is...Ch. 22.1 - Prob. 4P Ch. 22.1 - Prob. 5P Ch. 22.2 - Prob. 6P Ch. 22.2 - Problem 24.7 Draw the products formed in each...Ch. 22.4 - Prob. 15P Ch. 22.4 - Prob. 16P Ch. 22.5 - Problem 24.16 What ester is formed when each...

Solution Summary: The author explains that aldol reaction is the condensation reaction of the organic chemistry.

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Chapter 22 Solutions