EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
12th Edition
ISBN: 9781119233664
Author: Snyder
Publisher: VST
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Chapter 22, Problem 44P

The following reaction sequence represents an elegant method of synthesis of 2-deoxy-D-ribose, IV, published by D. C. C. Smith in 1955:

Chapter 22, Problem 44P, 22.44	The following reaction sequence represents an elegant method of synthesis of 2-deoxy-D-ribose,

(a) What are the structures of II and III?

(b) Propose a mechanism for the conversion of III to IV.

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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