The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis - trans isomerism are to be stated. Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis -isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond. To determine: The compounds that have same physical properties.

Question

Part II Calculate λ max of the following compounds using wood ward- Fiecer rules a) b) c) d) e) OH OH dissolved in dioxane Br Br dissolved in methanol. NH₂ OCH 3 OH

Answer 1

Question

Chapter 22, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Part II Calculate λ max of the following compounds using wood ward- Fiecer rules a) b) c) d) e) OH OH dissolved in dioxane Br Br dissolved in methanol. NH₂ OCH 3 OH

6. Match each of the lettered items in the column on the left with the most appropriate numbered item(s) in the column on the right. Some of the numbered items may be used more than once and some not at all. a. Z = 37 1. b. Mn 2. C. Pr element in period 5 and group 14 element in period 5 and group 15 d. S e. [Rn] 7s¹ f. d block metal 3. highest metallic character of all the elements 4. paramagnetic with 5 unpaired electrons 5. 4f36s2 6. isoelectronic with Ca²+ cation 7. an alkaline metal 8. an f-block element

Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.

Answer 2

Question

Chapter 22, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Answer 3

Question

Chapter 22, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Answer 4

Question

Chapter 22, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

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Answer 5

Chapter 22, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

Answer 6

Chapter 22, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

Answer 7

Chapter 22, Problem 34E

(a)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compounds that have same physical properties.

Answer 8

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

Answer 9

(b)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The trans isomer among the given compounds.

Answer 10

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

Answer 11

(c)

Interpretation Introduction

Interpretation: The compounds that would have same physical properties; which are trans isomers and those compounds that do not exhibit cis-trans isomerism are to be stated.

Concept introduction: Structural isomerism occurs when two compounds have same number of atoms but the spatial arrangement of the atoms is different from each other. These isomers have the same formula but their properties are different. In cis-isomers, the substituents of the double bonded carbons are on the same side of the double bond but in trans isomer, they are on opposite side of double bond.

To determine: The compound that will not undergo cis-trans isomerism.

Answer 12

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Answer 23

Ch. 22 - What is a hydrocarbon? What is the difference...Ch. 22 - Prob. 2RQ Ch. 22 - What are aromatic hydrocarbons? Benzene exhibits...Ch. 22 - Summarize the nomenclature rules for alkanes,...Ch. 22 - What functional group distinguishes each of the...Ch. 22 - Distinguish between isomerism and resonance....Ch. 22 - Prob. 7RQ Ch. 22 - Prob. 8RQ Ch. 22 - Prob. 9RQ Ch. 22 - Prob. 10RQ

Solution Summary: The author explains that structural isomerism occurs when two compounds have the same number of atoms but the spatial arrangement is different from each other.

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Chapter 22 Solutions