ORGANIC CHEMISTRYPKGDRL+MLCRL MDL
3rd Edition
ISBN: 9781119416746
Author: Klein
Publisher: WILEY
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Question
Chapter 22, Problem 33PP
Interpretation Introduction
Interpretation: Classification of nitrogen atom in spermine as primary, secondary or tertiary
Concept Introduction:
If nitrogen atom is attached to two hydrogen atoms in a compound, it is called primary amine. If nitrogen atom is attached to one hydrogen atoms in a compound, it is called secondary amine. If nitrogen atom is attached to three alkyl groups and no hydrogen atoms in a compound, it is called tertiary amine.
To find: Classify the nitrogen atom in spermine as primary, secondary or tertiary amine
Categorize the nitrogen atom as primary amine in spermine
Expert Solution & Answer
Answer to Problem 33PP
Classification of nitrogen atom in spermine as primary, secondary or tertiary amine is
Explanation of Solution
The given compound, spermine contains totally four nitrogen atoms. Among them, two of each nitrogen atom is connected with two hydrogen atoms. So, it belongs to primary amine.
Categorize the nitrogen atom as secondary amine in spermine
The given compound, spermine contains totally four nitrogen atoms. Among them, two of each nitrogen atom is connected with one hydrogen atom. So, it belongs to secondary amine.
Therefore, classification of nitrogen atom in spermine as primary, secondary or tertiary amine is
Conclusion
Conclusion
Classification of nitrogen atom in spermine as primary, secondary or tertiary amine should be done by using the concept of number of hydrogen atoms attached to nitrogen atom.
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Please answer the question and provide a detailed drawing of the structure. If there will not be a new C – C bond, then the box under the drawing area will be checked.
Will the following reaction make a molecule with a new C – C bond as its major product:
Draw the major organic product or products, if the reaction will work. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry.
Please do not use AI. AI cannot "see" the molecules properly, and it therefore gives the wrong answer while giving incorrect descriptions of the visual images we're looking at. All of these compounds would be produced (I think). In my book, I don't see any rules about yield in this case, like explaining that one product would be present in less yield for this reason or that reason. Please explain why some of these produce less yield than others.
Chapter 22 Solutions
ORGANIC CHEMISTRYPKGDRL+MLCRL MDL
Ch. 22.2 - Prob. 1LTSCh. 22.2 - Prob. 1PTSCh. 22.2 - Prob. 2PTSCh. 22.2 - Prob. 3ATSCh. 22.3 - Prob. 4CCCh. 22.3 - Prob. 5CCCh. 22.3 - Prob. 6CCCh. 22.3 - Prob. 7CCCh. 22.3 - Prob. 8CCCh. 22.3 - Prob. 9CC
Ch. 22.4 - Prob. 10CCCh. 22.4 - Prob. 11CCCh. 22.5 - Prob. 2LTSCh. 22.5 - Prob. 12PTSCh. 22.5 - Prob. 13ATSCh. 22.6 - Prob. 3LTSCh. 22.6 - Prob. 14PTSCh. 22.6 - Prob. 15ATSCh. 22.7 - Prob. 4LTSCh. 22.7 - Prob. 16PTSCh. 22.7 - Prob. 17PTSCh. 22.7 - Prob. 18PTSCh. 22.7 - Prob. 19ATSCh. 22.8 - Prob. 20CCCh. 22.8 - Prob. 21CCCh. 22.8 - Prob. 22CCCh. 22.9 - Prob. 5LTSCh. 22.9 - Prob. 23PTSCh. 22.9 - Prob. 24ATSCh. 22.10 - Prob. 25CCCh. 22.11 - Prob. 26CCCh. 22.11 - Prob. 6LTSCh. 22.11 - Prob. 27PTSCh. 22.11 - Prob. 28ATSCh. 22.12 - Prob. 29CCCh. 22.12 - Prob. 30CCCh. 22.13 - Prob. 31CCCh. 22.13 - Prob. 32CCCh. 22 - Prob. 33PPCh. 22 - Prob. 34PPCh. 22 - Prob. 35PPCh. 22 - Prob. 36PPCh. 22 - Prob. 37PPCh. 22 - Prob. 38PPCh. 22 - Prob. 39PPCh. 22 - Prob. 40PPCh. 22 - Prob. 41PPCh. 22 - Prob. 42PPCh. 22 - Prob. 43PPCh. 22 - Prob. 44PPCh. 22 - Prob. 45PPCh. 22 - Prob. 46PPCh. 22 - Prob. 47PPCh. 22 - Prob. 48PPCh. 22 - Prob. 49PPCh. 22 - Prob. 50PPCh. 22 - Prob. 51PPCh. 22 - Prob. 52PPCh. 22 - Prob. 53PPCh. 22 - Prob. 54PPCh. 22 - Prob. 55PPCh. 22 - Prob. 56PPCh. 22 - Prob. 57PPCh. 22 - Prob. 58PPCh. 22 - Prob. 59PPCh. 22 - Prob. 60PPCh. 22 - Prob. 61PPCh. 22 - Prob. 62PPCh. 22 - Prob. 63PPCh. 22 - Prob. 64PPCh. 22 - Prob. 65PPCh. 22 - Prob. 66PPCh. 22 - Prob. 67PPCh. 22 - Prob. 68PPCh. 22 - Prob. 69PPCh. 22 - Prob. 70PPCh. 22 - Prob. 71PPCh. 22 - Prob. 72PPCh. 22 - Prob. 73IPCh. 22 - Prob. 74IPCh. 22 - Prob. 75IPCh. 22 - Prob. 76IPCh. 22 - Prob. 77IPCh. 22 - Prob. 78IPCh. 22 - Prob. 79IPCh. 22 - Prob. 80IPCh. 22 - Prob. 81IPCh. 22 - Prob. 82IPCh. 22 - Prob. 83IPCh. 22 - Prob. 84IPCh. 22 - Prob. 85IPCh. 22 - Prob. 86IPCh. 22 - Prob. 87IPCh. 22 - Prob. 88IPCh. 22 - Prob. 89IPCh. 22 - Prob. 90IPCh. 22 - Prob. 91IPCh. 22 - Prob. 92IPCh. 22 - Prob. 93IPCh. 22 - Prob. 94IPCh. 22 - Prob. 95IPCh. 22 - Prob. 96CPCh. 22 - Prob. 97CPCh. 22 - Prob. 98CPCh. 22 - Prob. 99CP
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