(a)
Interpretation: The product that is formed by the intramolecular aldol reaction of the given dicarbonyl compound followed by dehydration is to be drawn.
Concept introduction: The aldol reaction that takes place within the same molecule in the presence of strong base is known as intramolecular aldol reactions. This reaction generally takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate ion that acts as a nucleophile and the carbonyl carbon of the second carbonyl group acts as an electrophile.
(b)
Interpretation: The product that is formed by the intramolecular aldol reaction of the given dicarbonyl compound followed by dehydration is to be drawn.
Concept introduction: The aldol reaction that takes place within the same molecule in the presence of strong base is known as intramolecular aldol reactions. This reaction generally takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate ion that acts as a nucleophile and the carbonyl carbon of the second carbonyl group acts as an electrophile.
(c)
Interpretation: The product that is formed by the intramolecular aldol reaction of the given dicarbonyl compound followed by dehydration is to be drawn.
Concept introduction: The aldol reaction that takes place within the same molecule in the presence of strong base is known as intramolecular aldol reactions. This reaction generally takes place within the dicarbonyl compounds in which one carbonyl group forms the enolate ion that acts as a nucleophile and the carbonyl carbon of the second carbonyl group acts as an electrophile.
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Chapter 22 Solutions
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- Draw the aldol product formed from each compound.arrow_forwardDraw the product formed when each compound is treated with two equivalents of CH3CH2CH2CH2MgBr followed by H2O.arrow_forwardDraw the product formed when CH3CH2CH2CH2NH2 reacts with each carbonyl compound in the presence of mild acidarrow_forward
- Select the carbonyl compound which can form only a single enol via tautomerization. A. B. H C. D.arrow_forwardDraw the products obtained (including stereochemistry) when each compound is treated with LDA, followed by CH3I.arrow_forwardDraw the products formed (including stereoisomers) when each compound is reduced with NaBH4 in CH3OH.arrow_forward
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