Concept explainers
(a)
Interpretation:
The relationship between the fate of pyruvate under aerobic and anaerobic conditions has to be determined.
Concept Introduction:
Aerobic conditions are those conditions in which process occur in presence of oxygen or oxygen is used as a reactant to produce the product. Anaerobic conditions are those conditions in which the process occurs in absence of oxygen.
(b)
Interpretation:
The relationship between the role of the citric acid cycle in the catabolism of carbohydrates, fats, and proteins has to be determined.
Concept Introduction:
The citric acid cycle includes a series of biochemical reactions to form carbon dioxide and play an important role in energy production and biosynthesis. It is the last stage of carbohydrates, fats, and amino acids breakdown.
(c)
Interpretation:
The relationship between the structure of mitochondrion, the citric acid cycle, and ATP synthesis have to be determined.
Concept Introduction:
Mitochondria are capsule-shaped organelles similar to the size of a bacterial cell also known as the powerhouse of the cell. Mitochondria are double-membrane organelle surrounded by an outer mitochondrial membrane and an inner mitochondrial membrane. The space between the outer membrane and inner membranes is called intermembrane space.

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Chapter 22 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY
- What parameters are included in the specific rotation calculation of a pure substance based on measurement from a polarimeter? Select one or more: Density of the sample Pathlength of the sample container Enantiomeric excess of the sample Measured rotation of lightarrow_forwardV Determine whether the following molecule is a hemiacetal, acetal, or neither and select the appropriate box below. Also, highlight the hemiacetal or acetal carbon if there is one. Explanation O CH O Ohemiacetal Oacetal Oneither Check A 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Cer 000 Ararrow_forward1. Using Online resources and chemical structures hand draw four different organic compounds (not those already shown in your handout) that are chiral, optically active (a pair of enantiomers will count as one). Pay attention to correct stereochemistry 2. Write or type a short paragraph to Discuss the stereochemical relationship between the four compounds.arrow_forward
- 1. Using a Model set Build a model for the following compound [CHBRIF] 2. Build another model of the mirror image of your first molecule. 3. Place the two models next to each other and take a picture which shows the differences between the two models. 4. Determine the absolute stereochemistry R or S for the two models. 5. Write or type a paragraph to Discuss the stereochemical relationship between the two models of CHBгCIF. You must provide an explanation for your conclusions also provide a description for the colors used to representarrow_forwardThe specific rotation of a sample depends upon measured angle of rotation, the density of the sample, and the pathway length of the light. True Falsearrow_forwardConsider the molecule A,B, C and D shown below, (1 x 4) Br NH2 A OH Br 边 H B C D 1. Assign the R/S configuration to each chiral center and identify by circling all the chiral centers. 2. Draw an image for the enantiomer of each of the compounds A, B, C and D.arrow_forward
- Could you crystallize one enantiomer of mandelic acid from a racemic mixture (using the typical achiral solvents found in our lab) without preparing a diastereomeric salt? Why or why not? No, because both enantiomers have the same solubility in achiral solvents. than the other. ооо Yes, because one enantiomer has a higher melting point No, because both enantiomers are liquids. Yes, because one enantiomer is more crystalline than the other.arrow_forwardIf the literature value of specific rotation for a chiral compound is -53.6°, what is the enantiomeric excess of a compound with a measured specific rotation of -40.5°?arrow_forwardThe process to determine the configuration, starts by placing the lowest priority substituent toward the back. If the substituents pointing forward decrease in priority in a clockwise order, the configuration is S. If the substituents decrease in priority in a counterclockwise order, the configuration is R. True Falsearrow_forward
- In the drawing area below, create a hemiacetal with 1 hydroxyl group, 1 methoxy group, and a total of 3 carbon atoms. Click and drag to start drawing a structure. Explanation Check Х PO 18 Ar B © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibilityarrow_forwardPredict the product of the reaction below (3 pts). hydrazine Ph H₂NNH2 KOH Write the mechanism for the above reaction using curved arrows to show electron movements. show all intermediates in the process (7 pts).arrow_forward↓ Feedback (8/10) Draw the major product of this reaction. Ignore inorganic byproducts. Incorrect, 2 attempts remaining N H3O+ 0 × Select to Draw + V Retryarrow_forward
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