(a) Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

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Answer 1

Question

Chapter 22, Problem 22.66P

Interpretation Introduction

(a)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(b)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(c)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

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Two methods convert an alkyl halide to a carboxylic acid having one more carbon atom. Depending on the structure of the alkyl halide, one or both of these methods may be employed. For each alkyl halide, write out a stepwise sequence that converts it to a carboxylic acid with one more carbon atom. If both methods work, draw both routes. If one method cannot be used, state why it can't.

Please answer both the parts or don't answer give a small explanation.

When trichloroacetaldehyde is dissolved in water, almost all of it is converted to the hydrate. Chloral hydrate, the product of the reaction, is a sedative that can be lethal. A cocktail laced with it is known—in detective novels, at least—as a “Mickey Finn.” Explain why an aqueous solution of trichloroacetaldehyde is almost all hydrate.

Answer 2

Question

Chapter 22, Problem 22.66P

Interpretation Introduction

(a)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(b)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(c)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

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Answer 3

Question

Chapter 22, Problem 22.66P

Interpretation Introduction

(a)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(b)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(c)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

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Answer 4

Question

Chapter 22, Problem 22.66P

Interpretation Introduction

(a)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(b)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(c)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

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Answer 5

Chapter 22, Problem 22.66P

Interpretation Introduction

(a)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(b)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Interpretation Introduction

(c)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Answer 6

Chapter 22, Problem 22.66P

Interpretation Introduction

(a)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Answer 7

Chapter 22, Problem 22.66P

Interpretation Introduction

(a)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Answer 8

Interpretation Introduction

(b)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Answer 9

Interpretation Introduction

(b)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Answer 10

Interpretation Introduction

(c)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Answer 11

Interpretation Introduction

(c)

Interpretation: A stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. In nucleophilc acyl substitution reaction, nucleophile takes the position of leaving group.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 22 - Prob. 22.1P Ch. 22 - Draw the three possible resonance structures for...Ch. 22 - Prob. 22.3P Ch. 22 - Give an IUPAC or common name for each compound. a....Ch. 22 - Problem 22.5 Draw the structure corresponding to...Ch. 22 - Problem 22.6 Explain why the boiling point of is...Ch. 22 - Problem 22.7 How would the compounds in each pair...Ch. 22 - Problem 22.8 Deduce the structures of compounds ...Ch. 22 - Problem 22.9 Without reading ahead in Chapter 22,...Ch. 22 - Rank the compounds in each group in order of...

Solution Summary: The author explains that a stepwise sequence that converts given alkyl halide to carboxylic acid is to be stated by the use to suitable method.

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Chapter 22 Solutions