Structure of cis-trans isomer of the following complexes has to be drawn. (a) [ C o ( N O 2 ) 4 ( N H 3 ) 2 ] − (b) [ C o ( N H 3 ) 5 ( N O ) 2 ] 2 + (c) [ C o ( N H 3 ) 6 ] 3 + (d) [ C r ( N H 3 ) 5 C l ] 2 + Concept Introduction: A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 1

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai

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Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling point, choose 2 next to the substance with the next highest boiling point, and so on. substance C D chemical symbol, chemical formula or Lewis structure. CH,-N-CH, CH, H H 10: H C-C-H H H H Cale H 10: H-C-C-N-CH, Bri CH, boiling point (C) Сен (C) B (Choose

Answer 2

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 3

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 4

Question

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

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Answer 5

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 6

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 7

Chapter 22, Problem 22.54QP

(a)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Structure of cis-trans isomer of the following complexes has to be drawn.

(a) [Co(NO2)4(NH3)2]− (b) [Co(NH3)5(NO)2]2+ (c) [Co(NH3)6]3+ (d) [Cr(NH3)5Cl]2+

Concept Introduction:

A compound that has same molecular formula but different structural formula is said to exhibit isomerism. Co-ordination compounds exhibit cis-trans isomerism which is a type of geometric isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains the structure of cis-trans isomer of the following complexes.

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Chapter 22 Solutions