Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781285969770
Author: Ball
Publisher: Cengage
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Chapter 22, Problem 22.44E

Are the following processes examples of homogeneous or heterogeneous catalysis? (a) Hydrolysis of immiscible ethyl acetate ( l ) in an aqueous basic solution. (b) Conversion of NO X gases to N 2 and O 2 by platinum metal. (c) Decomposition of atmospheric ozone by NO gas. (d) Oxidation of ethyl alcohol, C 2 H 5 OH , by the enzyme alcohol dehydrogenase, ADH, to acetaldehyde in the body. (e) Solid-state conversion of C (graphite) to C (diamond) by transition metal additives at high pressure.

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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