Chemistry: An Atoms-Focused Approach (Second Edition)
Chemistry: An Atoms-Focused Approach (Second Edition)
2nd Edition
ISBN: 9780393614053
Author: Thomas R. Gilbert, Rein V. Kirss, Stacey Lowery Bretz, Natalie Foster
Publisher: W. W. Norton & Company
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Chapter 22, Problem 22.30QA
Interpretation Introduction

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The following ions in order of increasing ionic radius; Br-,O2-,K+, and Ca2+.

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The molar absorptivity of a protein in water at 280 nm can be estimated within ~5-10% from its content of the amino acids tyrosine and tryptophan and from the number of disulfide linkages (R-S-S-R) between cysteine residues:   Ε280 nm (M-1 cm-1) ≈ 5500 nTrp + 1490 nTyr + 125 nS-S   where nTrp is the number of tryptophans, nTyr is the number of tyrosines, and nS-S is the number of disulfide linkages. The protein human serum transferrin has 678 amino acids including 8 tryptophans, 26 tyrosines, and 19 disulfide linkages. The molecular mass of the most dominant for is 79550.   Predict the molar absorptivity of transferrin. Predict the absorbance of a solution that’s 1.000 g/L transferrin in a 1.000-cm-pathlength cuvet. Estimate the g/L of a transferrin solution with an absorbance of 1.50 at 280 nm.
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Chapter 22 Solutions

Chemistry: An Atoms-Focused Approach (Second Edition)

Ch. 22 - Prob. 22.11QACh. 22 - Prob. 22.12QACh. 22 - Prob. 22.13QACh. 22 - Prob. 22.14QACh. 22 - Prob. 22.15QACh. 22 - Prob. 22.16QACh. 22 - Prob. 22.17QACh. 22 - Prob. 22.18QACh. 22 - Prob. 22.19QACh. 22 - Prob. 22.20QACh. 22 - Prob. 22.21QACh. 22 - Prob. 22.22QACh. 22 - Prob. 22.23QACh. 22 - Prob. 22.24QACh. 22 - Prob. 22.25QACh. 22 - Prob. 22.26QACh. 22 - Prob. 22.27QACh. 22 - Prob. 22.28QACh. 22 - Prob. 22.29QACh. 22 - Prob. 22.30QACh. 22 - Prob. 22.31QACh. 22 - Prob. 22.32QACh. 22 - Prob. 22.33QACh. 22 - Prob. 22.34QACh. 22 - Prob. 22.35QACh. 22 - Prob. 22.36QACh. 22 - Prob. 22.37QACh. 22 - Prob. 22.38QACh. 22 - Prob. 22.39QACh. 22 - Prob. 22.40QACh. 22 - Prob. 22.41QACh. 22 - Prob. 22.42QACh. 22 - Prob. 22.43QACh. 22 - Prob. 22.44QACh. 22 - Prob. 22.45QACh. 22 - Prob. 22.46QACh. 22 - Prob. 22.47QACh. 22 - Prob. 22.48QACh. 22 - Prob. 22.49QACh. 22 - Prob. 22.50QACh. 22 - Prob. 22.51QACh. 22 - Prob. 22.52QACh. 22 - Prob. 22.53QACh. 22 - Prob. 22.54QACh. 22 - Prob. 22.55QACh. 22 - Prob. 22.56QACh. 22 - Prob. 22.57QACh. 22 - Prob. 22.58QACh. 22 - Prob. 22.59QACh. 22 - Prob. 22.60QACh. 22 - Prob. 22.61QACh. 22 - Prob. 22.62QACh. 22 - Prob. 22.63QACh. 22 - Prob. 22.64QACh. 22 - Prob. 22.65QACh. 22 - Prob. 22.66QACh. 22 - Prob. 22.67QACh. 22 - Prob. 22.68QACh. 22 - Prob. 22.69QACh. 22 - Prob. 22.70QACh. 22 - Prob. 22.71QACh. 22 - Prob. 22.72QACh. 22 - Prob. 22.73QACh. 22 - Prob. 22.74QACh. 22 - Prob. 22.75QACh. 22 - Prob. 22.76QACh. 22 - Prob. 22.77QACh. 22 - Prob. 22.78QACh. 22 - Prob. 22.79QACh. 22 - Prob. 22.80QACh. 22 - Prob. 22.81QACh. 22 - Prob. 22.82QACh. 22 - Prob. 22.83QACh. 22 - Prob. 22.84QACh. 22 - Prob. 22.85QACh. 22 - Prob. 22.86QA
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