The geometric and optical isomer structures for the given complex ion need to draw. Concept Introduction : Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound. Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds. Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds. Optical isomers: Optical isomers are non-superimposable mirror images. Plane-polarized light: Light that oscillates in a single plane. To Identify: Geometric isomers and optical isomer structure for the given complex ion to be drawn.

Question

Want to see the full answer?

Answer 1

Question

Chapter 22, Problem 22.25QP

a)

Interpretation Introduction

Interpretation: The geometric and optical isomer structures for the given complex ion need to draw.

Concept Introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

To Identify: Geometric isomers and optical isomer structure for the given complex ion to be drawn.

b)

Interpretation Introduction

Interpretation: The geometric and optical isomer structures for the given complex ion need to draw.

Concept Introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

To Identify: Geometric isomers and optical isomer structure for the given complex ion to be drawn.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Draw the structures of the four geometrical isomers of [Co(NH3)2(en)BrCl]+. Two of these are optically active. Identify these, and draw the structures of their optical isomers.

Draw the energy diagram for d-orbital electron configuration in the octahedral field for each of the following complex ions. Indicate whether the ion is paramagnetic or diamagnetic: (a) [Cr(H2O)6]3+ (H2O is a weak-field ligand) (b) [Cr(NH3)6]3+ (NH3 is a strong-field ligand) (c) [CoF6]3– (F– is a weak-field ligand) (d) [Co(CN)6]3– (CN– is a strong-field ligand) (e) [Ni(H2O)6]2+ (H2O is a weak-field ligand) (f) [Ni(en)3]2+ (en is a strong-field ligand)

Determine if each of the following metal complexes is chiral and therefore has an optical isomer: (a) square planar [Pd(en)(CN)2], (b) octahedral [Ni(en)(NH3)4]2+, (c) octahedral cis-[V(en)2ClBr].