The oxidation number of the metal in the given compound has to be determined. Concept introduction: Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions. Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond. Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Question

Draw the products of this reduction of a ketone with sodium borohydride. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, where applicableIgnore any inorganic byproducts. 1) NaBH4 2) HCI/H2O Select to Draw

Answer 1

Question

Chapter 22, Problem 10PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

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Draw the products of this reduction of a ketone with sodium borohydride. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, where applicableIgnore any inorganic byproducts. 1) NaBH4 2) HCI/H2O Select to Draw

Why do you think people who live at high altitudes are advised to add salt to water when boiling food like pasta? What mole fraction of NaCl is needed to raise the boiling point of H2O by 3˚C? Does the amount of salt added to water (typically about one teaspoon to four quarts of water) substantially change the boiling point? (Kb (H2O) = 0.51˚C/molal.)

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Answer 2

Question

Chapter 22, Problem 10PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

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Answer 3

Question

Chapter 22, Problem 10PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

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Answer 4

Question

Chapter 22, Problem 10PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

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Answer 5

Chapter 22, Problem 10PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 6

Chapter 22, Problem 10PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 7

Chapter 22, Problem 10PS

(a)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 8

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 9

(b)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 10

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 11

(c)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 12

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 13

(d)

Interpretation Introduction

Interpretation: The oxidation number of the metal in the given compound has to be determined.

Concept introduction:

Coordination compounds: The compounds having coordination covalent bonds which form when metal ions react with polar molecules or anions.

Ligands: The ions or molecules that forms coordination covalent bond with metal ions in a coordination compound. Ligands should have minimum one lone pair of electron, where it donates two electrons to the metal. Metal atom accepts the electron pair from a ligand forming a coordination bond.

Oxidation number: The total number of electrons in an atom after losing or gaining electrons to make a bond with another atom. It indicates the charge of an ion.

Answer 14

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Answer 25

Ch. 22.1 - Prob. 1RC Ch. 22.2 - Prob. 1Q Ch. 22.2 - 2. Describe the unit cell of austenite. Ch. 22.2 - Prob. 3Q Ch. 22.2 - Prob. 1RC Ch. 22.2 - Prob. 2RC Ch. 22.3 - (a) What is the formula of a complex ion composed...Ch. 22.3 - (a) Determine the metals oxidation number and...Ch. 22.3 - Name the following coordination compounds. (a)...Ch. 22.3 - Prob. 1RC

Solution Summary: The author explains that the oxidation number of the metal in the given compound has to be determined.

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Chapter 22 Solutions