a) N -Methyl propanamide and N, N - dimethyl acetamide. Interpretation: To distinguish spectroscopically between the following isomer pairs.

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Answer 1

Question

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Expert Solution & Answer

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Answer 3

Question

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Expert Solution & Answer

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Answer 4

Question

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

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Answer 5

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 6

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 7

Chapter 21.SE, Problem 64AP

Interpretation Introduction

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 8

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 9

Interpretation Introduction

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 10

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 11

Interpretation Introduction

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 12

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 13

Interpretation Introduction

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 21.1 - Give IUPAC names for the following substances:Ch. 21.1 - Draw structures corresponding to the following...Ch. 21.2 - Prob. 3P Ch. 21.2 - Rank the compounds in each of the following sets...Ch. 21.2 - Predict the products of the following nucleophilic...Ch. 21.2 - Prob. 6P Ch. 21.3 - Prob. 7P Ch. 21.3 - If the following molecule is treated with acid...Ch. 21.4 - How might you prepare the following esters using a...Ch. 21.4 - Prob. 10P

a) N -Methyl propanamide and N, N - dimethyl acetamide. Interpretation: To distinguish spectroscopically between the following isomer pairs.

a) N-Methyl propanamide and N, N- dimethyl acetamide. Interpretation: To distinguish spectroscopically between the following isomer pairs.

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide. Interpretation: To distinguish spectroscopically between the following isomer pairs.

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride. Interpretation: To distinguish spectroscopically between the following isomer pairs.

d) Ethyl propanate and propyl acetate. Interpretation: To distinguish spectroscopically between the following isomer pairs.

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Chapter 21 Solutions

a) N-Methyl propanamide and N, N- dimethyl acetamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

b) 5- hydroxyl pentananitrile and cyclobutane carboxamide.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

c) 4- chloro butanoic acid and 3- methoxy propanoyl chloride.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.

d) Ethyl propanate and propyl acetate.

Interpretation:

To distinguish spectroscopically between the following isomer pairs.