(a) Interpretation: The product that is formed by the reaction of 2 − bromopentan − 3 − one with Li 2 O 3 , LiBr , DMF is to be drawn. Concept introduction: The bimolecular elimination reaction that favours the removal of a HX substituent from an alkyl halide that needs a base to remove H from carbon adjacent to the leaving group that in turn forms a double bond is termed E 2 elimination reaction.

Question

Want to see the full answer?

Answer 1

Question

Chapter 21.7, Problem 14P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with Li2O3, LiBr, DMF is to be drawn.

Concept introduction: The bimolecular elimination reaction that favours the removal of a HX substituent from an alkyl halide that needs a base to remove H from carbon adjacent to the leaving group that in turn forms a double bond is termed E2 elimination reaction.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3CH2NH2 is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3SH is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Draw the major organic substitution product or products for (2R,3S)-2-bromo-3-methylpentane reacting with the given nucleophile. Clearly drawn the stereochemistry, including a wedged bond, a dashed bond and two in-plane bonds at each stereogenic center. Omit any byproducts. Bri CH3CH2O- (conc.) Draw the major organic product or products.

Tartaric acid (C4H6O6) is a diprotic weak acid. A sample of 875 mg tartaric acid are dissolved in 100 mL water and titrated with 0.994 M NaOH. How many mL of NaOH are needed to reach the first equivalence point? How many mL of NaOH are needed to reach the second equivalence point?

Including activity, calculate the solubility of Pb(IO3)2 in a matrix of 0.020 M Mg(NO3)2.

Answer 2

Question

Chapter 21.7, Problem 14P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with Li2O3, LiBr, DMF is to be drawn.

Concept introduction: The bimolecular elimination reaction that favours the removal of a HX substituent from an alkyl halide that needs a base to remove H from carbon adjacent to the leaving group that in turn forms a double bond is termed E2 elimination reaction.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3CH2NH2 is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3SH is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 21.7, Problem 14P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with Li2O3, LiBr, DMF is to be drawn.

Concept introduction: The bimolecular elimination reaction that favours the removal of a HX substituent from an alkyl halide that needs a base to remove H from carbon adjacent to the leaving group that in turn forms a double bond is termed E2 elimination reaction.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3CH2NH2 is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3SH is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 21.7, Problem 14P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with Li2O3, LiBr, DMF is to be drawn.

Concept introduction: The bimolecular elimination reaction that favours the removal of a HX substituent from an alkyl halide that needs a base to remove H from carbon adjacent to the leaving group that in turn forms a double bond is termed E2 elimination reaction.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3CH2NH2 is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3SH is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 21.7, Problem 14P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with Li2O3, LiBr, DMF is to be drawn.

Concept introduction: The bimolecular elimination reaction that favours the removal of a HX substituent from an alkyl halide that needs a base to remove H from carbon adjacent to the leaving group that in turn forms a double bond is termed E2 elimination reaction.

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3CH2NH2 is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3SH is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 6

Chapter 21.7, Problem 14P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with Li2O3, LiBr, DMF is to be drawn.

Concept introduction: The bimolecular elimination reaction that favours the removal of a HX substituent from an alkyl halide that needs a base to remove H from carbon adjacent to the leaving group that in turn forms a double bond is termed E2 elimination reaction.

Answer 7

Chapter 21.7, Problem 14P

Interpretation Introduction

(a)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with Li2O3, LiBr, DMF is to be drawn.

Concept introduction: The bimolecular elimination reaction that favours the removal of a HX substituent from an alkyl halide that needs a base to remove H from carbon adjacent to the leaving group that in turn forms a double bond is termed E2 elimination reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3CH2NH2 is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3CH2NH2 is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 10

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3SH is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 11

Interpretation Introduction

(c)

Interpretation: The product that is formed by the reaction of 2−bromopentan−3−one with CH3SH is to be drawn.

Concept introduction: The substitution reaction involves the replacement of one functional group by other functional group. In nucleophilic substitution an electron rich species attack the species that is deficient in electrons. The electrophile and the leaving group together form a substrate. The nucleophile attacks over the substrate and there occurs the removal of leaving group from the substrate.

The nucleophilic reaction that consists of bimolecular as well as bond-making and bond-breaking steps is termed as SN2 reactions. This is a one-step reaction in which both nucleophile and substrate participate in the rate determining step.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 21.2 - Problem 23.1 Draw the enol or keto tautomer(s) of...Ch. 21.2 - Problem 23.3 When phenylacetaldehyde is dissolved...Ch. 21.3 - Prob. 5P Ch. 21.3 - Problem 23.5 Which bonds in the following...Ch. 21.3 - Prob. 7P Ch. 21.3 - Prob. 8P Ch. 21.3 - Prob. 9P Ch. 21.4 - Prob. 10P Ch. 21.5 - Prob. 11P Ch. 21.7 - Problem 23.11 Draw the products of each...

Solution Summary: The author describes the bimolecular elimination reaction that favours the removal of a HX substituent from an alkyl halide.

Concept explainers

Want to see the full answer?

Chapter 21 Solutions