(a) Interpretation: The reason corresponding to the fact that after the reaction of ( R ) − 2 − methylcyclohexanone with NaOH in the presence of H 2 O , the optically active solution gradually loses optical activity is to be stated. Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers. The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture. The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

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Answer 1

Question

Chapter 21.5, Problem 11P

Interpretation Introduction

(a)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−2−methylcyclohexanone with NaOH in the presence of H2O, the optically active solution gradually loses optical activity is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Interpretation Introduction

(b)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−3−methylcyclohexanone with NaOH in the presence of H2O, the solution remains optically active is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

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Consider a solution of 0.00304 moles of 4-nitrobenzoic acid (pKa = 3.442) dissolved in 25 mL water and titrated with 0.0991 M NaOH. Calculate the pH at the equivalence point

Answer 2

Question

Chapter 21.5, Problem 11P

Interpretation Introduction

(a)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−2−methylcyclohexanone with NaOH in the presence of H2O, the optically active solution gradually loses optical activity is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Interpretation Introduction

(b)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−3−methylcyclohexanone with NaOH in the presence of H2O, the solution remains optically active is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

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Answer 3

Question

Chapter 21.5, Problem 11P

Interpretation Introduction

(a)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−2−methylcyclohexanone with NaOH in the presence of H2O, the optically active solution gradually loses optical activity is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Interpretation Introduction

(b)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−3−methylcyclohexanone with NaOH in the presence of H2O, the solution remains optically active is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

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Answer 4

Question

Chapter 21.5, Problem 11P

Interpretation Introduction

(a)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−2−methylcyclohexanone with NaOH in the presence of H2O, the optically active solution gradually loses optical activity is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Interpretation Introduction

(b)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−3−methylcyclohexanone with NaOH in the presence of H2O, the solution remains optically active is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

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Answer 5

Chapter 21.5, Problem 11P

Interpretation Introduction

(a)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−2−methylcyclohexanone with NaOH in the presence of H2O, the optically active solution gradually loses optical activity is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Interpretation Introduction

(b)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−3−methylcyclohexanone with NaOH in the presence of H2O, the solution remains optically active is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Answer 6

Chapter 21.5, Problem 11P

Interpretation Introduction

(a)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−2−methylcyclohexanone with NaOH in the presence of H2O, the optically active solution gradually loses optical activity is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Answer 7

Chapter 21.5, Problem 11P

Interpretation Introduction

(a)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−2−methylcyclohexanone with NaOH in the presence of H2O, the optically active solution gradually loses optical activity is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Answer 8

Interpretation Introduction

(b)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−3−methylcyclohexanone with NaOH in the presence of H2O, the solution remains optically active is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Answer 9

Interpretation Introduction

(b)

Interpretation: The reason corresponding to the fact that after the reaction of (R)−3−methylcyclohexanone with NaOH in the presence of H2O, the solution remains optically active is to be stated.

Concept introduction: The stereoisomers that possess the mirror images of each other which are not superimposable or not identical to each other are termed as enantiomers.

The process of producing the equal mixture of possible enantiomers if any compound undergoes a transformation then this process is termed as racemization. The resultant mixture is known as racemic mixture.

The phenomenon by which a chiral molecule is observed to rotate the polarized light in either a clockwise direction or anticlockwise direction is called optical activity of that molecule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21.2 - Problem 23.1 Draw the enol or keto tautomer(s) of...Ch. 21.2 - Problem 23.3 When phenylacetaldehyde is dissolved...Ch. 21.3 - Prob. 5P Ch. 21.3 - Problem 23.5 Which bonds in the following...Ch. 21.3 - Prob. 7P Ch. 21.3 - Prob. 8P Ch. 21.3 - Prob. 9P Ch. 21.4 - Prob. 10P Ch. 21.5 - Prob. 11P Ch. 21.7 - Problem 23.11 Draw the products of each...

Solution Summary: The author explains that the optically active solution loses optical activity after the reaction of (R)-2-methylcyclohexanone

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