LL ORG CHEM
LL ORG CHEM
6th Edition
ISBN: 9781264840083
Author: SMITH
Publisher: MCG
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Chapter 21.3, Problem 7P
Interpretation Introduction

Interpretation: The increasing order of acidity for the labeled CH2 protons is to be shown.

Concept Introduction: The most acidic hydrogen (H) atom or proton is the one which can be easily eliminated from the molecule. In case of carbonyl group, the CH bond that is present on the αcarbon atom of carbonyl group is highly acidic as compared to sp3 hybridized carbon-hydrogen bonds due to the formation of resonance stabilized enolate.

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16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してし
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Chapter 21 Solutions

LL ORG CHEM

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