
Concept explainers
Interpretation: The structure of the conjugate acid of acetamide is to be drawn. An explanation corresponding to the fact that in acetamide protonation does not occur at nitrogen is to be explained. The
Concept introduction: According to Bronsted-Lowry theory, when an acid donates a proton the species formed is known as conjugate base and when the base accepts a proton the species formed is known as conjugate acid. The conjugate base has negative charge or lone pair of electrons present over it.
The acidity and basicity of a compound is influenced by the resonance. The amount of stability depends on the delocalization of the charge through the resonance. The delocalization of electrons due to presence of lone pair and double bond is called resonating structure.
To determine: The structure of the conjugate acid of acetamide,

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Chapter 2 Solutions
ORGANIC CHEMISTRY
- Consider the solubility products (Ksp values) for the following compounds:SrSO4 (Ksp = 7.6 x 10−7), BaSO4 (Ksp = 1.5 x 10−9), SrCO3 (Ksp = 7.0 x 10−10), BaCO3 (Ksp = 1.6 x 10−9)Which anion is the harder base, CO32− or SO42−? Justify your answer.arrow_forwardQ1: a) Arrange the compounds in order of decreasing pKa, highest first. ОН ΟΗ ῸΗ дон ОН ОН CI Brarrow_forward(4 pts - 2 pts each part) A route that can be taken to prepare a hydrophobic (water-repellent) aerogel is to start with trichloromethylsilane, CH3SiCl3 as the silicon source. a. What is the chemical reaction that this undergoes to form a product with Si-OH groups? Write as complete of a chemical equation as you can. CI CI-SI-CH3 CI b. The formation of a byproduct is what drives this reaction - what is the byproduct (if you didn't already answer it in part (a)) and how/why does it form?arrow_forward
- b) Circle the substrate that would not efficiently generate a Grignard reagent upon reaction with Mg in ether. CI Br ד c) Circle the Grignard reagents that contain incompatible functional groups. MgBr HO MgBr MgBr MgBr MgBr HO MgBrarrow_forwardQ2: Predict all organic product(s), including stereoisomers when applicable. PCC OH a) CH2Cl2 Page 2 of 5 Chem 0310 Organic Chemistry 1 HW Problem Sets b) .OH Na2Cr2O7, H+ OH PCC CH2Cl2 c) OHarrow_forwardd) Circle the substrates that will give an achiral product after a Grignard reaction with CH3MgBr. Harrow_forward
- Explain why the S-F bond strength is 367 kJ/mol in SF2 and 329 kJ/mol in SF6.arrow_forwardWould Si(CH3)3F react with AgCl? If so, write out the balanced chemical equation. If not,explain why no reaction would take place.arrow_forwardNH3 reacts with boron halides (BX3 where X = F, Cl, Br, or I) to form H3N-BX3 complexes.Which of these complexes will have the strongest N-B bond? Justify your answerarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning

