EBK INTRO.CHEMISTRY (NASTA EDITION)
9th Edition
ISBN: 9781337678032
Author: ZUMDAHL
Publisher: CENGAGE CO
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Chapter 21, Problem 80AP
Interpretation Introduction
Interpretation:
Interpret and complete the following statement.
‘The linkage present between sugar and phosphoric acid is phosphate - linkage’.
Concept Introduction:
A
Ester linkage is produced from condensation of 2 hydroxyl group by the removal of water molecule. This results in creation of -o- linkage.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 21 Solutions
EBK INTRO.CHEMISTRY (NASTA EDITION)
Ch. 21.9 - Prob. 1CTCh. 21 - Differentiate among primary, secondary, and...Ch. 21 - Prob. 2ALQCh. 21 - Prob. 3ALQCh. 21 - Prob. 4ALQCh. 21 - Prob. 5ALQCh. 21 - Prob. 6ALQCh. 21 - Prob. 7ALQCh. 21 - Prob. 8ALQCh. 21 - Prob. 9ALQ
Ch. 21 - Prob. 10ALQCh. 21 - Prob. 11ALQCh. 21 - Prob. 1QAPCh. 21 - Prob. 2QAPCh. 21 - Prob. 3QAPCh. 21 - Prob. 4QAPCh. 21 - Prob. 5QAPCh. 21 - Prob. 6QAPCh. 21 - Prob. 7QAPCh. 21 - Prob. 8QAPCh. 21 - Prob. 9QAPCh. 21 - . How many unique amino acid sequences are...Ch. 21 - Prob. 11QAPCh. 21 - Prob. 12QAPCh. 21 - Prob. 13QAPCh. 21 - Prob. 14QAPCh. 21 - Prob. 15QAPCh. 21 - Prob. 16QAPCh. 21 - Prob. 17QAPCh. 21 - Prob. 18QAPCh. 21 - Prob. 19QAPCh. 21 - . What protein is responsible for the transport of...Ch. 21 - Prob. 21QAPCh. 21 - Prob. 22QAPCh. 21 - Prob. 23QAPCh. 21 - Prob. 24QAPCh. 21 - . How does the efficiency of an enzyme compare...Ch. 21 - Prob. 26QAPCh. 21 - Prob. 27QAPCh. 21 - . Describe the lock-and-key model for enzymes. Why...Ch. 21 - Prob. 29QAPCh. 21 - Prob. 30QAPCh. 21 - Prob. 31QAPCh. 21 - Prob. 32QAPCh. 21 - Prob. 33QAPCh. 21 - Prob. 34QAPCh. 21 - Prob. 35QAPCh. 21 - Prob. 36QAPCh. 21 - Prob. 37QAPCh. 21 - Prob. 38QAPCh. 21 - Prob. 39QAPCh. 21 - Prob. 40QAPCh. 21 - Prob. 41QAPCh. 21 - Prob. 42QAPCh. 21 - Prob. 43QAPCh. 21 - Prob. 44QAPCh. 21 - Prob. 45QAPCh. 21 - Prob. 46QAPCh. 21 - Prob. 47QAPCh. 21 - Prob. 48QAPCh. 21 - Prob. 49QAPCh. 21 - Prob. 50QAPCh. 21 - . What is a steroid? What basic ring structure 15...Ch. 21 - Prob. 52QAPCh. 21 - Prob. 53QAPCh. 21 - Prob. 54QAPCh. 21 - Prob. 55APCh. 21 - Prob. 56APCh. 21 - Prob. 57APCh. 21 - Prob. 58APCh. 21 - Prob. 59APCh. 21 - Prob. 60APCh. 21 - Prob. 61APCh. 21 - Prob. 62APCh. 21 - Prob. 63APCh. 21 - Prob. 64APCh. 21 - Prob. 65APCh. 21 - Prob. 66APCh. 21 - Prob. 67APCh. 21 - Prob. 68APCh. 21 - Prob. 69APCh. 21 - Prob. 70APCh. 21 - Prob. 71APCh. 21 - Prob. 72APCh. 21 - Prob. 73APCh. 21 - Prob. 74APCh. 21 - Prob. 75APCh. 21 - Prob. 76APCh. 21 - Prob. 77APCh. 21 - Prob. 78APCh. 21 - Prob. 79APCh. 21 - Prob. 80APCh. 21 - Prob. 81APCh. 21 - Prob. 82APCh. 21 - Prob. 83APCh. 21 - Prob. 84APCh. 21 - Prob. 85APCh. 21 - Prob. 86APCh. 21 - Prob. 87APCh. 21 - Prob. 88APCh. 21 - Prob. 89APCh. 21 - Prob. 90APCh. 21 - Prob. 91APCh. 21 - Prob. 92APCh. 21 - Prob. 93APCh. 21 - Prob. 94APCh. 21 - Prob. 95APCh. 21 - Prob. 96APCh. 21 - . How many possible primary structures exist for a...Ch. 21 - Prob. 98APCh. 21 - Prob. 99APCh. 21 - Prob. 100APCh. 21 - Prob. 101APCh. 21 - Prob. 102APCh. 21 - Prob. 103APCh. 21 - Prob. 104APCh. 21 - Prob. 105APCh. 21 - Prob. 106AP
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