EBK CHEMISTRY
4th Edition
ISBN: 8220102797864
Author: Burdge
Publisher: YUZU
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Chapter 21, Problem 56QP
Why is it dangerous to idle a car's engine in a poorly ventilated place, such as the garage?
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ
Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this
system:
?
rise
Under these conditions, will the pressure of N2 tend to rise or fall?
☐ x10
fall
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of N2 will tend to rise, can that be
changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of N2 will tend to fall, can that be changed to a tendency to rise
by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
☐
atm
☑
5
00.
18
Ar
i need help with the following
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ
Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions
about this system:
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
atm
☑
18
Ar
Chapter 21 Solutions
EBK CHEMISTRY
Ch. 21.1 - Practice Problem ATTEMPT Calculate the wavelength...Ch. 21.1 - Practice Problem BUILD Which of the following...Ch. 21.1 - Prob. 1PPCCh. 21.1 - Prob. 1CPCh. 21.1 - Prob. 2CPCh. 21.2 - Practice Problem ATTEMPT which of the following is...Ch. 21.2 - Practice Problem BUILD Both O 2 and O 3 exhibit...Ch. 21.2 - Prob. 1PPCCh. 21.2 - 21.2.1 What maximum wavelength (in nm) of fight is...Ch. 21.2 - What process gives rise to the aurora borealis and...
Ch. 21.3 - Prob. 1PPACh. 21.3 - Practice Problem BUILD How long will it take for...Ch. 21.3 - Prob. 1PPCCh. 21.8 - Prob. 1CPCh. 21.8 - Prob. 2CPCh. 21 - Prob. 1QPCh. 21 - Prob. 2QPCh. 21 - Prob. 3QPCh. 21 - Prob. 4QPCh. 21 - Referring to Table 21.1, calculate the mole...Ch. 21 - Prob. 6QPCh. 21 - Prob. 7QPCh. 21 - Calculate the mass (in kg) of nitrogen, oxygen,...Ch. 21 - 21.9 What process gives rise to the aurora...Ch. 21 - Prob. 10QPCh. 21 - The highly reactive OH radical (a species with an...Ch. 21 - The green color observed in the aurora borealis is...Ch. 21 - Prob. 13QPCh. 21 - Prob. 14QPCh. 21 - Prob. 15QPCh. 21 - Prob. 16QPCh. 21 - What causes the polar ozone holes?Ch. 21 - How do volcanic eruptions contribute to ozone...Ch. 21 - Prob. 19QPCh. 21 - Discuss the effectiveness of some of the CFC...Ch. 21 - Prob. 21QPCh. 21 - Prob. 22QPCh. 21 - Prob. 23QPCh. 21 - Prob. 24QPCh. 21 - Prob. 25QPCh. 21 - Prob. 26QPCh. 21 - Prob. 27QPCh. 21 - Prob. 28QPCh. 21 - Prob. 29QPCh. 21 - Prob. 30QPCh. 21 - Prob. 31QPCh. 21 - Prob. 32QPCh. 21 - Describe three human activities that generate...Ch. 21 - Prob. 34QPCh. 21 - Prob. 35QPCh. 21 - Prob. 36QPCh. 21 - What effects do CFCs and their substitutes have on...Ch. 21 - Why are CFCs more effective greenhouse gases than...Ch. 21 - Prob. 39QPCh. 21 - Calcium oxide or quicklime ( CaO ) is used in...Ch. 21 - Prob. 41QPCh. 21 - 21.42 List three detrimental effects of acid...Ch. 21 - 21.43 Briefly discuss two industrial processes...Ch. 21 - Discuss ways to curb acid rain.Ch. 21 - Prob. 45QPCh. 21 - Prob. 46QPCh. 21 - Prob. 47QPCh. 21 - Identify the gas that is responsible for the brown...Ch. 21 - 21.49 The safety limits of ozone and carbon...Ch. 21 - Prob. 50QPCh. 21 - Prob. 51QPCh. 21 - 21.52 The gas-phase decomposition of peroxyacetyl...Ch. 21 - 21.53 On a smoggy day in a certain city. the ozone...Ch. 21 - Prob. 54QPCh. 21 - What is the best way to deal with indoor...Ch. 21 - Why is it dangerous to idle a car's engine in a...Ch. 21 - Prob. 57QPCh. 21 - Prob. 58QPCh. 21 - Prob. 59QPCh. 21 - Prob. 60APCh. 21 - Prob. 61APCh. 21 - Prob. 62APCh. 21 - Prob. 63APCh. 21 - Prob. 64APCh. 21 - 21.65 How are past temperatures determined from...Ch. 21 - The balance between SO 2 and SO 3 is important in...Ch. 21 - Prob. 67APCh. 21 - 21.68 A glass of water initially at pH 7.0 is...Ch. 21 - Prob. 69APCh. 21 - 21.70 Instead of monitoring carbon dioxide,...Ch. 21 - Describe the removal of SO 2 by CaO (to form CaSO...Ch. 21 - 21.72 Which of the following settings is the most...Ch. 21 - Prob. 73APCh. 21 - Peroxyacetyl nitrate (PAN) undergoes thermal...Ch. 21 - Prob. 75APCh. 21 - Prob. 76APCh. 21 - 21.77 The carbon dioxide level in the atmosphere...Ch. 21 - Prob. 78APCh. 21 - Prob. 79APCh. 21 - 21.80 A person was found dead of carbon monoxide...Ch. 21 - Prob. 81APCh. 21 - Prob. 82APCh. 21 - The molar heat capacity of a diatomic molecule is...Ch. 21 - Prob. 84APCh. 21 - Prob. 85APCh. 21 - Prob. 86APCh. 21 - Prob. 1SEPPCh. 21 - Prob. 2SEPPCh. 21 - Prob. 3SEPPCh. 21 - Prob. 4SEPP
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- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HCN is a weak acid. acids: 0.29 mol of NaOH is added to 1.0 L of a 1.2M HCN solution. bases: ☑ other: 0.09 mol of HCl is added to acids: 1.0 L of a solution that is bases: 0.3M in both HCN and KCN. other: 0,0,... ? 00. 18 Ar 日arrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1arrow_forward
- Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?arrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. 2.2 mol of NaOH is added to 1.0 L of a 1.4M HF solution. acids: П bases: Х other: ☐ ப acids: 0.51 mol of KOH is added to 1.0 L of a solution that is bases: 1.3M in both HF and NaF. other: ☐ 00. 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: N2O4 (g) 2NO2 (g) AG⁰ = 5.4 kJ Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of N2O4 tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. yes no 0.42 atm ☑ 5 0/5 ? مله Ararrow_forward
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