The d orbital splitting diagrams for the given octahedral complex ions are to be drawn. Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t 2g orbitals and higher energy orbitals. Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t 2g orbitals. To draw: The d orbital splitting diagrams for the octahedral complex ion Fe 2 + (high and low spin).

Question

For the titration of a divalent metal ion (M2+) with EDTA, the stoichiometry of the reaction is typically: 1:1 (one mole of EDTA per mole of metal ion) 2:1 (two moles of EDTA per mole of metal ion) 1:2 (one mole of EDTA per two moles of metal ion) None of the above

Answer 1

Question

Chapter 21, Problem 51E

(a)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe2+ (high and low spin).

(b)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe3+ (high spin).

(c)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Ni2+.

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For the titration of a divalent metal ion (M2+) with EDTA, the stoichiometry of the reaction is typically: 1:1 (one mole of EDTA per mole of metal ion) 2:1 (two moles of EDTA per mole of metal ion) 1:2 (one mole of EDTA per two moles of metal ion) None of the above

Please help me solve this reaction.

Indicate the products obtained by mixing 2,2-dimethylpropanal with acetaldehyde and sodium ethoxide in ethanol.

Answer 2

Question

Chapter 21, Problem 51E

(a)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe2+ (high and low spin).

(b)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe3+ (high spin).

(c)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Ni2+.

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Answer 3

Question

Chapter 21, Problem 51E

(a)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe2+ (high and low spin).

(b)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe3+ (high spin).

(c)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Ni2+.

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Answer 4

Question

Chapter 21, Problem 51E

(a)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe2+ (high and low spin).

(b)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe3+ (high spin).

(c)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Ni2+.

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Answer 5

Chapter 21, Problem 51E

(a)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe2+ (high and low spin).

(b)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe3+ (high spin).

(c)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Ni2+.

Answer 6

Chapter 21, Problem 51E

(a)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe2+ (high and low spin).

Answer 7

Chapter 21, Problem 51E

(a)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe2+ (high and low spin).

Answer 8

(b)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe3+ (high spin).

Answer 9

(b)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Fe3+ (high spin).

Answer 10

(c)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Ni2+.

Answer 11

(c)

Interpretation Introduction

Interpretation: The d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

Concept introduction: Weak field ligand that has small crystal field splitting energy gives high spin due to the presence of maximum unpaired electrons in lower energy t2g orbitals and higher energy orbitals.

Strong field ligand that has large crystal field splitting energy gives low spin due to the presence of maximum paired electrons in lower energy t2g orbitals.

To draw: The d orbital splitting diagrams for the octahedral complex ion Ni2+.

Answer 12

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Answer 23

Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Prob. 4RQ Ch. 21 - Prob. 5RQ Ch. 21 - Prob. 6RQ Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains how the d orbital splitting diagrams for the given octahedral complex ions are to be drawn.

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Chapter 21 Solutions