EBK GENERAL CHEMISTRY
11th Edition
ISBN: 8220103631259
Author: Bissonnette
Publisher: YUZU
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Chapter 21, Problem 4E
Describe two methods for determining the identity of an unknown compound that is either
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Describe the principle of resonance and give a set of Lewis Structures to illustrate your explanation.
Don't used hand raiting
It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
Chapter 21 Solutions
EBK GENERAL CHEMISTRY
Ch. 21 - Prob. 1ECh. 21 - Use information from the chapter to write chemical...Ch. 21 - Prob. 3ECh. 21 - Describe two methods for determining the identity...Ch. 21 - Arrange the following compounds in the expected...Ch. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - A lithium battery used in a cardiac pacemaker has...Ch. 21 - Prob. 9ECh. 21 - Prob. 10E
Ch. 21 - The standard Gibbs energies of formation, rG , for...Ch. 21 - Prob. 12ECh. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Write chemical equations for the reactions you...Ch. 21 - Without performing detailed calculations, indicate...Ch. 21 - Prob. 20ECh. 21 - With respect to decomposition to MO(s) and SO2(g)...Ch. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Methane and sulfur vapor react to form carbon...Ch. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Write plausible chemical equations for the (a)...Ch. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Aqueous tin(II) ion, Sn2+(aq) , is a good reducing...Ch. 21 - Would you expect the reaction of Sn(s) and Cl2(g)...Ch. 21 - Prob. 54ECh. 21 - Prob. 55IAECh. 21 - The following series of observations is made: (1)...Ch. 21 - Prob. 57IAECh. 21 - Prob. 58IAECh. 21 - Prob. 59IAECh. 21 - Prob. 60IAECh. 21 - Lithium superoxide, LiO2(s) , has never been...Ch. 21 - Prob. 62IAECh. 21 - Prob. 63IAECh. 21 - Prob. 64IAECh. 21 - Use data from Appendix D (Table D-2) to calculate...Ch. 21 - Prob. 66IAECh. 21 - A particular water sample contains 56.9 ppm SO42-...Ch. 21 - An aluminum production cell of the type pictured...Ch. 21 - Prob. 69IAECh. 21 - Prob. 70IAECh. 21 - Prob. 71IAECh. 21 - Prob. 72IAECh. 21 - Prob. 73IAECh. 21 - Prob. 74IAECh. 21 - Prob. 75IAECh. 21 - Would you expect the lattice energy of MgS(s) to...Ch. 21 - Prob. 77IAECh. 21 - Prob. 78FPCh. 21 - Prob. 79FPCh. 21 - Prob. 80SAECh. 21 - Briefly describe each of the following ideas,...Ch. 21 - Explain the important distinction between each...Ch. 21 - Prob. 83SAECh. 21 - Prob. 84SAECh. 21 - Predict the products of the following reactions:...Ch. 21 - A chemist knows that aluminum is more reactive...Ch. 21 - Listed are several pairs of substances. For some...Ch. 21 - Prob. 88SAECh. 21 - Prob. 89SAECh. 21 - Prob. 90SAECh. 21 - Prob. 91SAECh. 21 - Prob. 92SAECh. 21 - Prob. 93SAECh. 21 - Prob. 94SAECh. 21 - Prob. 95SAE
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 206 Pb 82 Express your answers as integers. Enter your answers separated by a comma. ▸ View Available Hint(s) VAΣ ΜΕ ΑΣΦ Np, N₁ = 82,126 Submit Previous Answers ? protons, neutronsarrow_forwardPlease draw the inverted chair forms of the products for the two equilibrium reactions shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No requirement to show or do calculations.] CH3 CH3 HH CH3 1 -CH3arrow_forward5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forward
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