Introductory Chemistry: Foundation - Text (Looseleaf)
9th Edition
ISBN: 9781337399623
Author: ZUMDAHL
Publisher: Cengage
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Chapter 21, Problem 42QAP
Interpretation Introduction
Interpretation:
Interpret the replication of DNA.
Concept Introduction:
Polynucleic acid such as DNA or RNA produced from
According to Chargaff rule, number of guanine present in a polynucleic acid is equivalent to number of cytosine present while number of adenine present in a polynucleic acid must be equivalent to number of thymine present and during unwinding bond between bases broken down to create fork like structure.
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13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Br.
COOH Br,
FCH COOH E
FeBr
ASOCI
B
NH
(CH,CO),OD Br₂
2
C
alcKOH
Find A to F (all)
Chapter 21 Solutions
Introductory Chemistry: Foundation - Text (Looseleaf)
Ch. 21.9 - Prob. 1CTCh. 21 - Differentiate among primary, secondary, and...Ch. 21 - Prob. 2ALQCh. 21 - Prob. 3ALQCh. 21 - Prob. 4ALQCh. 21 - Prob. 5ALQCh. 21 - Prob. 6ALQCh. 21 - Prob. 7ALQCh. 21 - Prob. 8ALQCh. 21 - Prob. 9ALQ
Ch. 21 - Prob. 10ALQCh. 21 - Prob. 11ALQCh. 21 - Prob. 1QAPCh. 21 - Prob. 2QAPCh. 21 - Prob. 3QAPCh. 21 - Prob. 4QAPCh. 21 - Prob. 5QAPCh. 21 - Prob. 6QAPCh. 21 - Prob. 7QAPCh. 21 - Prob. 8QAPCh. 21 - Prob. 9QAPCh. 21 - . How many unique amino acid sequences are...Ch. 21 - Prob. 11QAPCh. 21 - Prob. 12QAPCh. 21 - Prob. 13QAPCh. 21 - Prob. 14QAPCh. 21 - Prob. 15QAPCh. 21 - Prob. 16QAPCh. 21 - Prob. 17QAPCh. 21 - Prob. 18QAPCh. 21 - Prob. 19QAPCh. 21 - . What protein is responsible for the transport of...Ch. 21 - Prob. 21QAPCh. 21 - Prob. 22QAPCh. 21 - Prob. 23QAPCh. 21 - Prob. 24QAPCh. 21 - . How does the efficiency of an enzyme compare...Ch. 21 - Prob. 26QAPCh. 21 - Prob. 27QAPCh. 21 - . Describe the lock-and-key model for enzymes. Why...Ch. 21 - Prob. 29QAPCh. 21 - Prob. 30QAPCh. 21 - Prob. 31QAPCh. 21 - Prob. 32QAPCh. 21 - Prob. 33QAPCh. 21 - Prob. 34QAPCh. 21 - Prob. 35QAPCh. 21 - Prob. 36QAPCh. 21 - Prob. 37QAPCh. 21 - Prob. 38QAPCh. 21 - Prob. 39QAPCh. 21 - Prob. 40QAPCh. 21 - Prob. 41QAPCh. 21 - Prob. 42QAPCh. 21 - Prob. 43QAPCh. 21 - Prob. 44QAPCh. 21 - Prob. 45QAPCh. 21 - Prob. 46QAPCh. 21 - Prob. 47QAPCh. 21 - Prob. 48QAPCh. 21 - Prob. 49QAPCh. 21 - Prob. 50QAPCh. 21 - . What is a steroid? What basic ring structure 15...Ch. 21 - Prob. 52QAPCh. 21 - Prob. 53QAPCh. 21 - Prob. 54QAPCh. 21 - Prob. 55APCh. 21 - Prob. 56APCh. 21 - Prob. 57APCh. 21 - Prob. 58APCh. 21 - Prob. 59APCh. 21 - Prob. 60APCh. 21 - Prob. 61APCh. 21 - Prob. 62APCh. 21 - Prob. 63APCh. 21 - Prob. 64APCh. 21 - Prob. 65APCh. 21 - Prob. 66APCh. 21 - Prob. 67APCh. 21 - Prob. 68APCh. 21 - Prob. 69APCh. 21 - Prob. 70APCh. 21 - Prob. 71APCh. 21 - Prob. 72APCh. 21 - Prob. 73APCh. 21 - Prob. 74APCh. 21 - Prob. 75APCh. 21 - Prob. 76APCh. 21 - Prob. 77APCh. 21 - Prob. 78APCh. 21 - Prob. 79APCh. 21 - Prob. 80APCh. 21 - Prob. 81APCh. 21 - Prob. 82APCh. 21 - Prob. 83APCh. 21 - Prob. 84APCh. 21 - Prob. 85APCh. 21 - Prob. 86APCh. 21 - Prob. 87APCh. 21 - Prob. 88APCh. 21 - Prob. 89APCh. 21 - Prob. 90APCh. 21 - Prob. 91APCh. 21 - Prob. 92APCh. 21 - Prob. 93APCh. 21 - Prob. 94APCh. 21 - Prob. 95APCh. 21 - Prob. 96APCh. 21 - . How many possible primary structures exist for a...Ch. 21 - Prob. 98APCh. 21 - Prob. 99APCh. 21 - Prob. 100APCh. 21 - Prob. 101APCh. 21 - Prob. 102APCh. 21 - Prob. 103APCh. 21 - Prob. 104APCh. 21 - Prob. 105APCh. 21 - Prob. 106AP
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