MOLECULAR NATURE OF MATTER 7/E LL W/AC
7th Edition
ISBN: 9781119664796
Author: JESPERSEN
Publisher: WILEY
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Question
Chapter 21, Problem 39RQ
Interpretation Introduction
Interpretation:
The color of the light absorbed by a complexes appearing red and yellow are to be determined.
Concept Information:
Crystal field theory explains the bonding of complex ions.
Ligands are the molecules or ions that are bonded with a coordinate covalent bond to a metal ion.
The Crystal Field Stabilization Energy (CFSE) is the energy generated by distributing electrons in the
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MOLECULAR NATURE OF MATTER 7/E LL W/AC
Ch. 21 - Prob. 1PECh. 21 - Aluminum chloride crystallizes from aqueous...Ch. 21 - What is the formula of the complex ion that is...Ch. 21 - Prob. 4PECh. 21 - Prob. 5PECh. 21 - Prob. 6PECh. 21 - What is the coordination number of the metal ion...Ch. 21 - What is the coordination number of the metal ion...Ch. 21 - Prob. 9PECh. 21 - Prob. 10PE
Ch. 21 - Prob. 11PECh. 21 - Prob. 12PECh. 21 - The iron metal center in hemoglobin sits in an...Ch. 21 - Prob. 1RQCh. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Complex Ions Use Lewis structures to diagram the...Ch. 21 - Complex Ions
21.6 What must be true about the...Ch. 21 - Prob. 7RQCh. 21 - Complex Ions What is a chelate? Use Lewis...Ch. 21 - Prob. 9RQCh. 21 - Complex Ions Explain how a sale of EDTA4- can...Ch. 21 - Prob. 11RQCh. 21 - Complex Ions
21.12 The cobalt(III) ion, , forms a...Ch. 21 - Prob. 13RQCh. 21 - Complex Ions What is the chelate effect? How does...Ch. 21 - Prob. 15RQCh. 21 - Prob. 16RQCh. 21 - Prob. 17RQCh. 21 - Prob. 18RQCh. 21 - Prob. 19RQCh. 21 - Prob. 20RQCh. 21 - Prob. 21RQCh. 21 - Prob. 22RQCh. 21 - Prob. 23RQCh. 21 - Prob. 24RQCh. 21 - Coordination Number and Structure Draw (a) a...Ch. 21 - Prob. 26RQCh. 21 - Prob. 27RQCh. 21 - Prob. 28RQCh. 21 - Prob. 29RQCh. 21 - Prob. 30RQCh. 21 - Prob. 31RQCh. 21 - Bonding in Metal Complexes
21.32 On appropriate...Ch. 21 - Prob. 33RQCh. 21 - Prob. 34RQCh. 21 - Prob. 35RQCh. 21 - Prob. 36RQCh. 21 - Prob. 37RQCh. 21 - Prob. 38RQCh. 21 - Prob. 39RQCh. 21 - Prob. 40RQCh. 21 - Prob. 41RQCh. 21 - Prob. 42RQCh. 21 - Bonding in Metal Complexes What factors about the...Ch. 21 - Prob. 44RQCh. 21 - Bonding in Metal Complexes The complex [...Ch. 21 - Bonding in Metal Complexes
21.46 Consider the...Ch. 21 - Prob. 47RQCh. 21 - Prob. 48RQCh. 21 - Prob. 49RQCh. 21 - Prob. 50RQCh. 21 - Prob. 51RQCh. 21 - Biological Functions of Metals Ions
21.52 List...Ch. 21 - Prob. 53RQCh. 21 - Prob. 54RQCh. 21 - Prob. 55RQCh. 21 - Write the formula, including its correct charge,...Ch. 21 - Metal Complex Nomenclature How would the following...Ch. 21 - Metal Complex Nomenclature
21.58 How would the...Ch. 21 - Give IUPAC names for each of the following:...Ch. 21 - Prob. 60RQCh. 21 - Prob. 61RQCh. 21 - Prob. 62RQCh. 21 - Coordination Number and Structure
21.63 What is...Ch. 21 - Prob. 64RQCh. 21 - Draw a reasonable structure for (a) [ Zn(NH3)4 ]2+...Ch. 21 - Prob. 66RQCh. 21 - Prob. 67RQCh. 21 - 21.68 The following compound is called...Ch. 21 - Prob. 69RQCh. 21 - Isomers of Metal Complexes
*21.70 Below is a...Ch. 21 - Prob. 71RQCh. 21 - Prob. 72RQCh. 21 - Prob. 73RQCh. 21 - Prob. 74RQCh. 21 - Bonding in Metal Complexes
*21.75 In which complex...Ch. 21 - Prob. 76RQCh. 21 - Prob. 77RQCh. 21 - Prob. 78RQCh. 21 - Prob. 79RQCh. 21 - Prob. 80RQCh. 21 - Referring to the two ligands, A and B, described...Ch. 21 - Referring to the complexes in Problems 21.80 and...Ch. 21 - Prob. 83RQCh. 21 - Prob. 84RQCh. 21 - *21.85 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.86 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.87 ions can be either four coordinate or six...Ch. 21 - Prob. 88RQCh. 21 - Most of the first row transition metals form 2+...Ch. 21 - *21.90 Is the complex chiral? Illustrate your...Ch. 21 - The complex [PtCl2(NH3)2] can be obtained as two...Ch. 21 - Prob. 92RQCh. 21 - Prob. 93RQCh. 21 - The compound Cr2(NH3)3(H2O)3Cl is a neutral salt...Ch. 21 - Prob. 95RQCh. 21 - Prob. 96RQCh. 21 - Prob. 97RQCh. 21 - Prob. 98RQCh. 21 - Prob. 99RQCh. 21 - Platinum(IV) makes compounds with coordination...Ch. 21 - Prob. 101RQCh. 21 - Prob. 102RQ
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- An aqueous solution of [Rh(C2O4)3]3− is yellow. Predict the approximate wavelength and predominant color of light absorbed by the complex.arrow_forwardFor each d electron configuration, state the number of unpaired electrons expected in octahedral complexes. Give an example complex for each case. (Two answers are possible for some of these cases.) (a) d2 (b) d4 (c) d6 (d) d8arrow_forwardDefine the terms complex ion, ligand, and coordination number. Use an example to illustrate the use of these terms.arrow_forward
- Which of the following octahedral complexes show geometric isomerism? If geometric isomers are possible, draw their structures. (a) [Co(en)Cl4-] (b) [Ni(C2O4)2ClBr4-] (c) [Cd(NH3)2Cl42-]arrow_forwardWhat types of isomers are possible for the following compounds or complex ions? (a) K[Co(NH3)2Cl4] (b) Pt(en)Cl2 (square-planar) (c) [Co(NH3)5Cl]2+ (d) [Ru(phen)3]Cl3 (e) Na2[MnCl4] (tetrahedral) (f) [Co(NH3)5NO2)2+arrow_forwardWhat two first-row transition metals have unexpected electron configurations? A statement in the text says that first-row transition metal ions do not have 4s electrons. Why not? Why do transition metal ions often have several oxidation states, whereas representative metals generally have only one?arrow_forward
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