ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
ORGANIC CHEMISTRY-WILEYPLUS ACCESS PKG.
12th Edition
ISBN: 9781119766919
Author: Solomons
Publisher: WILEY
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Chapter 21, Problem 26P

In 1985, T. Katz (Columbia University) discovered that alkynes could participate in metathesis reactions via similar mechanistic processes as alkenes. Below is a reaction involving both an alkyne and an alkene. Draw a mechanism to account for the formation of the indicated diene product.

Chapter 21, Problem 26P, 21.26	In 1985, T. Katz (Columbia University) discovered that alkynes could participate in metathesis

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3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
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