Complete and detail mechanism for the given reaction is to determined. Concept introduction: In nucleophilic addition reaction nucleophile is attack on most electrophilic carbon atom results in the formation of new bond between nucleophile and electrophilic carbon atom. In case of proton transfer reaction proton is abstracted by the electronegative atom like oxygen, nitrogen etc. Heterolysis is the removal of water. In case of nucleophile elimination, good leaving group is expelled to reform the carbonyl bond. In intra molecular acid-catalyzed transesterification reaction one ester is transformed into another ester and ring formation takes place.

Question

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21, Problem 21.82P

Interpretation Introduction

Interpretation:

Complete and detail mechanism for the given reaction is to determined.

Concept introduction:

In nucleophilic addition reaction nucleophile is attack on most electrophilic carbon atom results in the formation of new bond between nucleophile and electrophilic carbon atom.

In case of proton transfer reaction proton is abstracted by the electronegative atom like oxygen, nitrogen etc.

Heterolysis is the removal of water.

In case of nucleophile elimination, good leaving group is expelled to reform the carbonyl bond.

In intra molecular acid-catalyzed transesterification reaction one ester is transformed into another ester and ring formation takes place.

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Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21, Problem 21.82P

Interpretation Introduction

Interpretation:

Complete and detail mechanism for the given reaction is to determined.

Concept introduction:

In nucleophilic addition reaction nucleophile is attack on most electrophilic carbon atom results in the formation of new bond between nucleophile and electrophilic carbon atom.

In case of proton transfer reaction proton is abstracted by the electronegative atom like oxygen, nitrogen etc.

Heterolysis is the removal of water.

In case of nucleophile elimination, good leaving group is expelled to reform the carbonyl bond.

In intra molecular acid-catalyzed transesterification reaction one ester is transformed into another ester and ring formation takes place.

Expert Solution & Answer

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Check out sample textbook solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21, Problem 21.82P

Interpretation Introduction

Interpretation:

Complete and detail mechanism for the given reaction is to determined.

Concept introduction:

In nucleophilic addition reaction nucleophile is attack on most electrophilic carbon atom results in the formation of new bond between nucleophile and electrophilic carbon atom.

In case of proton transfer reaction proton is abstracted by the electronegative atom like oxygen, nitrogen etc.

Heterolysis is the removal of water.

In case of nucleophile elimination, good leaving group is expelled to reform the carbonyl bond.

In intra molecular acid-catalyzed transesterification reaction one ester is transformed into another ester and ring formation takes place.

Expert Solution & Answer

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See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21, Problem 21.82P

Interpretation Introduction