(a) Interpretation: The structure of Pt(en) 2 complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex. Concept introduction: When considering transition metals , some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 1

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Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Consider a solution of 0.00304 moles of 4-nitrobenzoic acid (pKa = 3.442) dissolved in 25 mL water and titrated with 0.0991 M NaOH. Calculate the pH at the equivalence point

Answer 2

Question

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 3

Question

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 4

Question

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

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Answer 5

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 6

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 7

Chapter 21, Problem 21.73SP

Interpretation Introduction

(a)

Interpretation:

The structure of Pt(en)₂ complex and to determine the oxidation state, coordination number and coordination geometry of the metal in the complex.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of [Co(HO2)C5l]SO4 complex needs to be drawn and the oxidation state, coordination number and coordination geometry of the metal in the complex need to be determined.

Concept introduction:

When considering transition metals, some have partially filled or empty d orbitals. Therefore, they can form complexes with ligands. Ligands have lone pair electrons, which can donate to the central metal atom. Mostly, donor atom with lone pair electrons, of a ligand can form a coordinate bond to the central metal atom. The central metal with attached ligands is called as coordination sphere.

Answer 10

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

Solution Summary: The author explains the structure of Pt(en) 2 complex and the oxidation state, coordination number and coordination geometry of the metal in the complex.

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Chapter 21 Solutions