(a) Interpretation: The valance bond description of the bonding in [ A u C l 4 ] 2 (square planar) complex is to be determined. Concept introduction: The valance bond theory helps to determine the bonding between the two atoms.

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Answer 1

Question

Chapter 21, Problem 21.127SP

Interpretation Introduction

(a)

Interpretation:

The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(b)

Interpretation:

The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(c)

Interpretation:

The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(d)

Interpretation:

The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N

4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)

2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)

Answer 2

Question

Chapter 21, Problem 21.127SP

Interpretation Introduction

(a)

Interpretation:

The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(b)

Interpretation:

The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(c)

Interpretation:

The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(d)

Interpretation:

The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

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Answer 3

Question

Chapter 21, Problem 21.127SP

Interpretation Introduction

(a)

Interpretation:

The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(b)

Interpretation:

The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(c)

Interpretation:

The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(d)

Interpretation:

The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

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Answer 4

Question

Chapter 21, Problem 21.127SP

Interpretation Introduction

(a)

Interpretation:

The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(b)

Interpretation:

The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(c)

Interpretation:

The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(d)

Interpretation:

The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

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Answer 5

Chapter 21, Problem 21.127SP

Interpretation Introduction

(a)

Interpretation:

The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(b)

Interpretation:

The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(c)

Interpretation:

The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Interpretation Introduction

(d)

Interpretation:

The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Answer 6

Chapter 21, Problem 21.127SP

Interpretation Introduction

(a)

Interpretation:

The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Answer 7

Chapter 21, Problem 21.127SP

Interpretation Introduction

(a)

Interpretation:

The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

(a) Interpretation: The valance bond description of the bonding in [ A u C l 4 ] 2 (square planar) complex is to be determined. Concept introduction: The valance bond theory helps to determine the bonding between the two atoms.

Solution Summary: The author analyzes the valance bond description of the bonding in [AuCl_4]2.

Concept explainers

(a)

Interpretation:

The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

(b)

Interpretation:

The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

(c)

Interpretation:

The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

(d)

Interpretation:

The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

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Chapter 21 Solutions

(a) Interpretation: The valance bond description of the bonding in [ A u C l 4 ] 2 (square planar) complex is to be determined. Concept introduction: The valance bond theory helps to determine the bonding between the two atoms.

Solution Summary: The author analyzes the valance bond description of the bonding in [AuCl_4]2.

Concept explainers

(a) Interpretation: The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined. Concept introduction: The valance bond theory helps to determine the bonding between the two atoms.

(b) Interpretation: The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined. Concept introduction: The valance bond theory helps to determine the bonding between the two atoms.

(c) Interpretation: The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined. Concept introduction: The valance bond theory helps to determine the bonding between the two atoms.

(d) Interpretation: The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined. Concept introduction: The valance bond theory helps to determine the bonding between the two atoms.

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Chapter 21 Solutions

(a)

Interpretation:

The valance bond description of the bonding in [AuCl4]2 (square planar) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

(b)

Interpretation:

The valance bond description of the bonding in [Ag(NH3)2]+ (tetrahedral) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

(c)

Interpretation:

The valance bond description of the bonding in [Fe(H2O)6]2+ (high-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.

(d)

Interpretation:

The valance bond description of the bonding in [Fe(CN)6]4− (low-spin) complex is to be determined.

Concept introduction:

The valance bond theory helps to determine the bonding between the two atoms.