(a) Interpretation: To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester. Concept introduction: For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

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Answer 1

Question

Chapter 21, Problem 21.22P

Interpretation Introduction

(a)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Interpretation Introduction

(b)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

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What is the major organic product of the following nucleophilic acyl substitution reaction of an acid chloride below?

Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.

If a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.

Answer 2

Question

Chapter 21, Problem 21.22P

Interpretation Introduction

(a)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Interpretation Introduction

(b)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

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Answer 3

Question

Chapter 21, Problem 21.22P

Interpretation Introduction

(a)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Interpretation Introduction

(b)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

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Answer 4

Question

Chapter 21, Problem 21.22P

Interpretation Introduction

(a)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Interpretation Introduction

(b)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

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Answer 5

Chapter 21, Problem 21.22P

Interpretation Introduction

(a)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Interpretation Introduction

(b)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Answer 6

Chapter 21, Problem 21.22P

Interpretation Introduction

(a)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Answer 7

Chapter 21, Problem 21.22P

Interpretation Introduction

(a)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Answer 8

Interpretation Introduction

(b)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Answer 9

Interpretation Introduction

(b)

Interpretation:

To identify the appropriate base-solvent pair to accomplish a Claisen condensation with the ester.

Concept introduction:

For a Claisen condensation reaction, unwanted transesterification and saponification reactions can be avoided if the base that is added is the same as the alkoxide leaving group on the ester and if the alcohol solvent is the conjugate acid of that base.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

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Chapter 21 Solutions