OWLv2 with MindTap Reader, 4 terms (24 months) Printed Access Card for Zumdahl/Zumdahl's Chemistry, 9th
OWLv2 with MindTap Reader, 4 terms (24 months) Printed Access Card for Zumdahl/Zumdahl's Chemistry, 9th
9th Edition
ISBN: 9781285185446
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 21, Problem 100IP

a. In the absorption spectrum of the complex ion Cr(NCS)63−, there is a band corresponding to the absorption of a photon of light with an energy of 1.75 × 104 cm-1. Given 1 cm−1 = 1.986 × 10−23 J, what is the wavelength of this photon?

b. The Cr—N—C bond angle in Cr(NCS)63− is predicted to be 180°. What is the hybridization of the N atom in the Ncs- ligand when a Lewis acid-base reaction occurs between Cr3+ and NCs- that would give a 180° Cr−N−C bond angle? Cr(NCS)63− undergoes substitution by ethylenediamine (en) according to the equation

Cr ( NCS ) 6 3 + 2 en Cr ( NCS ) 2 ( en ) 2 + + 4 NCS

Does Cr(NCS)2(en)2+ exhibit geometric isomerism? Does Cr(NCS)2(en)2+ exhibit optical isomerism?

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Chapter 21 Solutions

OWLv2 with MindTap Reader, 4 terms (24 months) Printed Access Card for Zumdahl/Zumdahl's Chemistry, 9th

Ch. 21 - Prob. 1ALQCh. 21 - Prob. 2ALQCh. 21 - Prob. 3ALQCh. 21 - Prob. 4ALQCh. 21 - Prob. 5QCh. 21 - Four different octahedral chromium coordination...Ch. 21 - Prob. 7QCh. 21 - Prob. 8QCh. 21 - Prob. 9QCh. 21 - Prob. 10QCh. 21 - Prob. 11QCh. 21 - Prob. 12QCh. 21 - Prob. 13QCh. 21 - Prob. 14QCh. 21 - Which of the following ligands are capable of...Ch. 21 - Prob. 16QCh. 21 - Prob. 17QCh. 21 - Prob. 18QCh. 21 - Prob. 19QCh. 21 - Prob. 20QCh. 21 - Prob. 21ECh. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - When an aqueous solution of KCN is added to a...Ch. 21 - Prob. 31ECh. 21 - A coordination compound of cobalt(III) contains...Ch. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Give formulas for the following complex ions. a....Ch. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Amino acids can act as ligands toward transition...Ch. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Prob. 45ECh. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Prob. 49ECh. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Prob. 52ECh. 21 - The CrF64 ion is known to have four unpaired...Ch. 21 - Prob. 54ECh. 21 - Prob. 55ECh. 21 - The complex ion Fe(CN)63 is paramagnetic with one...Ch. 21 - Prob. 57ECh. 21 - Prob. 58ECh. 21 - Prob. 59ECh. 21 - Prob. 60ECh. 21 - The wavelength of absorbed electromagnetic...Ch. 21 - The complex ion NiCL42 has two unpaired electrons,...Ch. 21 - How many unpaired electrons are present in the...Ch. 21 - The complex ion PdCl42is diamagnetic. Propose a...Ch. 21 - Prob. 65ECh. 21 - Prob. 66ECh. 21 - Prob. 67ECh. 21 - Prob. 68ECh. 21 - Silver is sometimes found in nature as large...Ch. 21 - Prob. 70ECh. 21 - Prob. 71AECh. 21 - The compound cisplatin, Pt(NH3)2Cl2, has been...Ch. 21 - Prob. 73AECh. 21 - Prob. 74AECh. 21 - Prob. 75AECh. 21 - Prob. 76AECh. 21 - Prob. 77AECh. 21 - Name the following coordination compounds. a....Ch. 21 - Prob. 79AECh. 21 - Prob. 80AECh. 21 - Prob. 81AECh. 21 - Prob. 82AECh. 21 - Prob. 83CWPCh. 21 - Which of the following molecules exhibit(s)...Ch. 21 - Prob. 85CWPCh. 21 - The following table indicates the number of...Ch. 21 - Prob. 87CWPCh. 21 - Which of the following statement(s) is( are) true?...Ch. 21 - Consider the following complex ion, where A and B...Ch. 21 - Consider the pseudo-octahedral complex ion of...Ch. 21 - Prob. 91CPCh. 21 - Prob. 92CPCh. 21 - Chelating ligands often form more stable complex...Ch. 21 - Prob. 94CPCh. 21 - Prob. 95CPCh. 21 - Prob. 96CPCh. 21 - Sketch and explain the most likely crystal field...Ch. 21 - The ferrate ion, FeO42, is such a powerful...Ch. 21 - Ammonia and potassium iodide solutions are added...Ch. 21 - a. In the absorption spectrum of the complex ion...Ch. 21 - There are three salts that contain complex ions of...
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