The glycosidic linkages in chondroitin and heparin should be classified as a or β. Their location should be designated using the numbers. Concept Introduction: When numbering carbons in a cyclic carbohydrate, the numbering starts at acetal or hemiacetal carbon that means at the anomeric carbon, giving it the number 1. And the numbering continues clockwise. O atom in the ring is not given a number. If the glycosidic linkage is oriented down or below the plane of the ring, then it is an a glycoside. If the glycosidic linkage is oriented up, above the plane of the ring, then it is a β-glycoside.

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Answer 1

Question

Chapter 20.7, Problem 20.18P

Interpretation Introduction

Interpretation:

The glycosidic linkages in chondroitin and heparin should be classified as a or β. Their location should be designated using the numbers.

Concept Introduction:

When numbering carbons in a cyclic carbohydrate, the numbering starts at acetal or hemiacetal carbon that means at the anomeric carbon, giving it the number 1. And the numbering continues clockwise. O atom in the ring is not given a number.

If the glycosidic linkage is oriented down or below the plane of the ring, then it is an a glycoside. If the glycosidic linkage is oriented up, above the plane of the ring, then it is a β-glycoside.

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Identify the Functional Groups (FG) in the following molecules. Classify C atoms as tertiary, 30, or quaternary 40. Identify secondary 20 and tertiary, 30 hydrogen atoms. Please provide steps to undertand each labeling.

Answer 2

Question

Chapter 20.7, Problem 20.18P

Interpretation Introduction

Interpretation:

The glycosidic linkages in chondroitin and heparin should be classified as a or β. Their location should be designated using the numbers.

Concept Introduction:

When numbering carbons in a cyclic carbohydrate, the numbering starts at acetal or hemiacetal carbon that means at the anomeric carbon, giving it the number 1. And the numbering continues clockwise. O atom in the ring is not given a number.

If the glycosidic linkage is oriented down or below the plane of the ring, then it is an a glycoside. If the glycosidic linkage is oriented up, above the plane of the ring, then it is a β-glycoside.

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Answer 3

Question

Chapter 20.7, Problem 20.18P

Interpretation Introduction

Interpretation:

The glycosidic linkages in chondroitin and heparin should be classified as a or β. Their location should be designated using the numbers.

Concept Introduction:

When numbering carbons in a cyclic carbohydrate, the numbering starts at acetal or hemiacetal carbon that means at the anomeric carbon, giving it the number 1. And the numbering continues clockwise. O atom in the ring is not given a number.

If the glycosidic linkage is oriented down or below the plane of the ring, then it is an a glycoside. If the glycosidic linkage is oriented up, above the plane of the ring, then it is a β-glycoside.

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Answer 4

Question

Chapter 20.7, Problem 20.18P

Interpretation Introduction

Interpretation:

The glycosidic linkages in chondroitin and heparin should be classified as a or β. Their location should be designated using the numbers.

Concept Introduction:

When numbering carbons in a cyclic carbohydrate, the numbering starts at acetal or hemiacetal carbon that means at the anomeric carbon, giving it the number 1. And the numbering continues clockwise. O atom in the ring is not given a number.

If the glycosidic linkage is oriented down or below the plane of the ring, then it is an a glycoside. If the glycosidic linkage is oriented up, above the plane of the ring, then it is a β-glycoside.

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Answer 5

Chapter 20.7, Problem 20.18P

Interpretation Introduction

Interpretation:

The glycosidic linkages in chondroitin and heparin should be classified as a or β. Their location should be designated using the numbers.

Concept Introduction:

When numbering carbons in a cyclic carbohydrate, the numbering starts at acetal or hemiacetal carbon that means at the anomeric carbon, giving it the number 1. And the numbering continues clockwise. O atom in the ring is not given a number.

If the glycosidic linkage is oriented down or below the plane of the ring, then it is an a glycoside. If the glycosidic linkage is oriented up, above the plane of the ring, then it is a β-glycoside.

Answer 6

Chapter 20.7, Problem 20.18P

Interpretation Introduction

Interpretation:

The glycosidic linkages in chondroitin and heparin should be classified as a or β. Their location should be designated using the numbers.

Concept Introduction:

When numbering carbons in a cyclic carbohydrate, the numbering starts at acetal or hemiacetal carbon that means at the anomeric carbon, giving it the number 1. And the numbering continues clockwise. O atom in the ring is not given a number.

If the glycosidic linkage is oriented down or below the plane of the ring, then it is an a glycoside. If the glycosidic linkage is oriented up, above the plane of the ring, then it is a β-glycoside.

Answer 7

Chapter 20.7, Problem 20.18P

Interpretation Introduction

Interpretation:

The glycosidic linkages in chondroitin and heparin should be classified as a or β. Their location should be designated using the numbers.

Concept Introduction:

When numbering carbons in a cyclic carbohydrate, the numbering starts at acetal or hemiacetal carbon that means at the anomeric carbon, giving it the number 1. And the numbering continues clockwise. O atom in the ring is not given a number.

If the glycosidic linkage is oriented down or below the plane of the ring, then it is an a glycoside. If the glycosidic linkage is oriented up, above the plane of the ring, then it is a β-glycoside.

Answer 8

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Answer 11

Ch. 20.1 - Label the hemiacetal carbonthe carbon bonded to...Ch. 20.2 - Prob. 20.1PP Ch. 20.2 - Prob. 20.2P Ch. 20.2 - Prob. 20.3P Ch. 20.2 - Prob. 20.4P Ch. 20.2 - Prob. 20.5P Ch. 20.2 - Prob. 20.2PP Ch. 20.2 - Prob. 20.6P Ch. 20.2 - Prob. 20.7P Ch. 20.3 - Prob. 20.8P

Solution Summary: The author explains that the glycosidic linkages in chondroitin and heparin should be classified as a or.

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